Grazing incidence x-ray fluorescence and secondary ion mass spectrometry combined approach for the characterization of ultrashallow arsenic distribution in silicon Secondary ion mass spectrometry characterization of the diffusion properties of 17 elements implanted into silicon J.Approach to the characterization of through-oxide boron implantation by secondary ion mass spectrometry Study of pre-equilibrium sputter rates for ultrashallow depth profiling with secondary ion mass spectrometry Boron ultralow energy ͑0.2-3 keV͒ high dose ͑1 ϫ 10 15 cm −2 ͒ implants in single crystalline Si ͑100͒ were characterized by secondary ion mass spectrometry using an ultralow energy ͑0.35-0.5 keV͒ O 2 + ion primary beam and collecting positive secondary ions. In particular, the not fully oxidizing approaches ͑primary beam oblique incidence and ultrahigh vacuum analysis atmosphere͒ were investigated because they are expected to provide better accuracy on the profile shape, especially in the region between the surface and the native oxide/substrate interface. The main drawback represented by an early formation of roughness on the crater bottom has been overcome by combining the ion sputtering with the rotation of the sample during the analysis. The reduced formation of roughness ensures more stable sputtering conditions and a more stable erosion rate with a more accurate depth calibration. The measured dose values were then cross-checked comparing them with results of soft x-ray synchrotron radiation grazing incidence x-ray fluorescence.