An umpolung mechanism of B(pin)-mediated Cu/B rearrangement and origin of regioselectivity for NHC-Cu-catalyzed allylation of imines

Jia, Xinhua; Wang, Qiong; Liu, Jian-Biao; Wang, Wen‐Juan; Sun, Chuanzhi; Huang, Fang; Yang, Chong; Chen, Dezhan

doi:10.1039/d3qo00045a

Org. Chem. Front.

2023

DOI: 10.1039/d3qo00045a

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An umpolung mechanism of B(pin)-mediated Cu/B rearrangement and origin of regioselectivity for NHC-Cu-catalyzed allylation of imines

Xinhua Jia

Qiong Wang

Jian-Biao Liu

et al.

Abstract: The mechanism of NHC-Cu-catalyzed selective allylation of N-benzylideneaniline with three allyl bromides has been investigated by DFT calculations. The current calculations reveal an unprecedented mechanism of B(pin)-mediated Cu/B rearrangement. The...

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An umpolung mechanism of B(pin)-mediated Cu/B rearrangement and origin of regioselectivity for NHC-Cu-catalyzed allylation of imines

Abstract: The mechanism of NHC-Cu-catalyzed selective allylation of N-benzylideneaniline with three allyl bromides has been investigated by DFT calculations. The current calculations reveal an unprecedented mechanism of B(pin)-mediated Cu/B rearrangement. The...

Cited by 0 publications

References 57 publications

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