2019
DOI: 10.1038/s41467-019-13783-1
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An ultrathin ionomer interphase for high efficiency lithium anode in carbonate based electrolyte

Abstract: High coulombic efficiency and dendrite suppression in carbonate electrolytes remain challenges to the development of high-energy lithium ion batteries containing lithium metal anodes. Here we demonstrate an ultrathin (≤100 nm) lithium-ion ionomer membrane consisting of lithium-exchanged sulfonated polyether ether ketone embedded with polyhedral oligosilsesquioxane as a coating layer on copper or lithium for achieving efficient and stable lithium plating-stripping cycles in a carbonate-based electrolyte. Operan… Show more

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Cited by 69 publications
(34 citation statements)
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References 48 publications
(39 reference statements)
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“…S6 ). The Greater Caucasus posed the major barrier to human movements that is in agreement with the north–south cline in genetic variation (this study 26 , 49 . The genetic differentiation was the strongest between the populations from south and north of the Greater Caucasus main ridge, which once again indicates that the Greater Caucasus has been an important physical barrier for human dispersal since the last glacial period.…”
Section: Discussionsupporting
confidence: 79%
See 1 more Smart Citation
“…S6 ). The Greater Caucasus posed the major barrier to human movements that is in agreement with the north–south cline in genetic variation (this study 26 , 49 . The genetic differentiation was the strongest between the populations from south and north of the Greater Caucasus main ridge, which once again indicates that the Greater Caucasus has been an important physical barrier for human dispersal since the last glacial period.…”
Section: Discussionsupporting
confidence: 79%
“…The studies of genome-wide autosomal profiles as well as the mitochondrial and Y chromosomal haplogroups support that there is genetic continuity in the present-day southern Caucasus stretching back at least 13,000 years to the Late Upper Palaeolithic 8 , 25 . In the North Caucasus this continuity was disrupted due to post-bronze age admixture with populations from the Eurasian Steppe 26 . At present genetic differentiation between ethnic/subethnic groups in the Caucasus correlates with landscape permeability to human movement—as determined by terrain ruggedness, forest cover, and snow cover—rather than ethnic or linguistic boundaries 22 .…”
Section: Introductionmentioning
confidence: 99%
“…A third emerging model is based on evidence from rodents showing that lymphatic vessels appear to cross through the cribriform plate which may allow them to access the SAS directly [ 116 , 133 , 134 , 143 145 ]. This would offer an alternate pathway, one not necessarily associated with the olfactory nerves, for direct access of CSF and its constituents to the lymphatic vessels.…”
Section: Outflow Along Cranial Nervesmentioning
confidence: 99%
“…G4 structures have been associated with important biological functions including gene expression and regulation 5 , replication 6 , recombination, alternative splicing 7 , and genome stability 8 . In the eukaryotic genomes, G4s are mainly located at the telomeres 9 and gene regulatory regions such as promoters 10 and the untranslated regions (UTRs) 11 .…”
Section: Introductionmentioning
confidence: 99%