An oxidative alkylamination of 1,3,7‐triazapyrenes in the aqueous medium

Abstract

Abstract1,3,7‐Triazapyrene and 2‐methyl‐1,3,7‐triazapyrene have shown to react with a wide range of alkylamines in the presence of an oxidant (K3Fe(CN)6) in the water solution at room temperature to give rise to the corresponding 6‐mono‐alkyl(dialkyl)amino‐ and 6,8‐bis‐dialkylamino derivatives. J. Heterocyclic Chem., (2011).

Mechanochemically Induced Cross Dehydrogenative Coupling Reactions under Ball Milling

“…[9] The extensive development of transition-metal-free CH-functionalization reactions started only in the decade of 1960-1970 and first review article was published in 1976. [10] Now transition-metal-free CÀ H functionalization has become an obvious choice for the direct functionalization of (het)arenes, [11][12][13][14][15][16] including macrocycles. [17][18][19][20] The early and pioneering transition-metal-catalyzed CÀ H functionalization/activation reaction in…”