Abstract:The discovery of superconductivity at relatively higher temperatures in a non-cuprate system, LnFeAsO 1−x F x (Ln = lanthanides) has created tremendous activity among the reseachers in this field. This review is an overview on the present status and the future scope for iron pnictides. The various structural categories of iron based superconductors, the structural aspects, different preparation techniques of the material and the necessity for its optimization are discussed. The highlighting features of iron pn… Show more
“…The behavior of materials within this genus of the iron-pnictide family has, in some cases, been shown to be very sensitive to doping, impurities, and oxygen vacancies. 5,13,21,22 In our earlier study 4,6 on these samples, we measured lower transition temperatures, T SDW and T ST , relative to results from measurements of polycrystals and other single crystals at ambient pressure. 9,23 We compare the results of ambient pressure measurements on our single crystals of LaFeAsO to similar measurements discussed by Yan et al in the Results and Discussion section of this paper.…”
Section: Methodsmentioning
confidence: 82%
“…[3][4][5][6] As a function of chemical substitution or applied pressure, the phase diagrams of these materials exhibit a rich interplay of different phenomena, including structural transitions, commensurate and incommensurate spin-density wave (SDW) ordering, and high temperature superconductivity. [5][6][7][8][9][10][11][12][13] In several iron-based materials, the appearance of superconductivity occurs following a smooth suppression of SDW order. Among the materials in which such a continuous suppression is observed are, e.g., BaFe 2 As 2 (under both chemical substitution and applied pressure) 14 and fluorine-substituted CeFeAsO 1−x F x .…”
Measurements of electrical resistivity under applied pressure were performed on single crystalline samples of LaFeAsO grown in a molten NaAs flux. We observe a smooth suppression of spin-density wave order under nearly hydrostatic applied pressures up to 2.6 GPa and in quasi-hydrostatic pressures up to 14.7 GPa. Similar to some of the other reports on single and polycrystalline samples of LaFeAsO, these crystals exhibit a resistivity that increases as temperature is lowered. By fitting an Arrhenius law to the the semiconducting-like temperature dependence of the electrical resistivity, we extract an energy gap that is suppressed with pressure and vanishes near 10 GPa. This is accompanied by the emergence of a metallic temperature dependence of the electrical resistivity. A similar behavior is also observed in diamond anvil cell experiments carried out to ∼ 37 GPa. Complete transitions to a bulk superconducting phase are not observed in any of the experiments.
“…The behavior of materials within this genus of the iron-pnictide family has, in some cases, been shown to be very sensitive to doping, impurities, and oxygen vacancies. 5,13,21,22 In our earlier study 4,6 on these samples, we measured lower transition temperatures, T SDW and T ST , relative to results from measurements of polycrystals and other single crystals at ambient pressure. 9,23 We compare the results of ambient pressure measurements on our single crystals of LaFeAsO to similar measurements discussed by Yan et al in the Results and Discussion section of this paper.…”
Section: Methodsmentioning
confidence: 82%
“…[3][4][5][6] As a function of chemical substitution or applied pressure, the phase diagrams of these materials exhibit a rich interplay of different phenomena, including structural transitions, commensurate and incommensurate spin-density wave (SDW) ordering, and high temperature superconductivity. [5][6][7][8][9][10][11][12][13] In several iron-based materials, the appearance of superconductivity occurs following a smooth suppression of SDW order. Among the materials in which such a continuous suppression is observed are, e.g., BaFe 2 As 2 (under both chemical substitution and applied pressure) 14 and fluorine-substituted CeFeAsO 1−x F x .…”
Measurements of electrical resistivity under applied pressure were performed on single crystalline samples of LaFeAsO grown in a molten NaAs flux. We observe a smooth suppression of spin-density wave order under nearly hydrostatic applied pressures up to 2.6 GPa and in quasi-hydrostatic pressures up to 14.7 GPa. Similar to some of the other reports on single and polycrystalline samples of LaFeAsO, these crystals exhibit a resistivity that increases as temperature is lowered. By fitting an Arrhenius law to the the semiconducting-like temperature dependence of the electrical resistivity, we extract an energy gap that is suppressed with pressure and vanishes near 10 GPa. This is accompanied by the emergence of a metallic temperature dependence of the electrical resistivity. A similar behavior is also observed in diamond anvil cell experiments carried out to ∼ 37 GPa. Complete transitions to a bulk superconducting phase are not observed in any of the experiments.
“…Similar studies of iron-based superconductors with doping-dependent spin density waves (SDWs) would also be of benefit (see, e.g., recent Reviews [78,[269][270][271][272][273][274][275]), since CDW and SDW superconductors have similar, although not identical, properties [123][124][125].…”
“…Fe-As layers, which are negatively charged, and Ln-O layers (Ln: lanthanides), positively charged, are simply arranged along the c-axis. The Ln-O layers are insulating nature and the Fe-As layers are responsible from the conducting mechanism [14,15]. The FeSe phase, called as "11-phase" with T c =8 K, which is a derivative of FeAs family, is composed of tetrahedral stacks of Fe 2 Se 2 layers which have edge sharing peculiarity and behave as conducting layers similar to B 2 layers in MgB 2 metallic superconducting alloys [7,16].…”
Solid state synthesis of chitosan and its unsaturated derivatives for laser microfabrication of 3D scaffolds T A Akopova, T S Demina, V N Bagratashvili et al. K, respectively. The coherence length, , at the zero field, was calculated to be 1.94 nm and suggested a transparent intergrain boundaries peculiarity. The µ 0 H c2 (0)/k B T c rate shows higher value (3.36 T/K) than the Pauli limit (1.84 T/K) which suggests unconventional nature of superconductivity for the polycrystalline FeTe 0.5 Se 0.5 superconducting samples.
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