An Overview of Polymer‐Immobilized Chiral Catalysts and Synthetic Chiral Polymers

Itsuno, Shinichi

doi:10.1002/9781118063965.ch1

Cited by 10 publications

(1 citation statement)

References 114 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Moreover it can potentially allow for the recycling of the supported catalyst which is normally problematic in homogeneously catalysed reactions [25]. The immobilisation of individual ligands and catalysts on polymeric supports has been well investigated [26][27][28][29], but combinatorial solid-phase synthesis of large libraries of bidentate phosphorus ligands is rare. There have been several accounts of SPS of bidentate phosphorus ligands which are mainly aminophosphine-based structures [30][31][32][33][34].…”

Section: Introductionmentioning

confidence: 99%

Solid-Phase Synthesis and Catalytic Screening of Polystyrene Supported Diphosphines

et al. 2016

View full text Add to dashboard Cite

show abstract

Section: Introductionmentioning

confidence: 99%

Solid-Phase Synthesis and Catalytic Screening of Polystyrene Supported Diphosphines

et al. 2016

View full text Add to dashboard Cite

show abstract

Chiral Palladacycle Catalysts Generated on a Single‐Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4‐Epoxy‐1,4‐dihydronaphthalene

2014

View full text Add to dashboard Cite

Post-polymerization C À H activation of poly(quinoxaline-2,3-diyl)-based helically chiral phosphine ligands (PQXphos) with palladium(II) acetate afforded chiral phosphapalladacycles quantitatively. In situ generated palladacycles exhibited enantioselectivities up to 94 % ee in the palladium-catalyzed asymmetric ring-opening arylation of 1,4epoxy-1,4-dihydronaphthalenes with arylboronic acids.of 1,4-epoxy-1,4-dihydronaphthalenes with arylboronic acids. The application of these new chiral palladacycle catalysts to other catalytic reactions is now underway.

show abstract

Chiral Palladacycle Catalysts Generated on a Single‐Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4‐Epoxy‐1,4‐dihydronaphthalene

2014

View full text Add to dashboard Cite

Post-polymerization CH activation of poly(quinoxaline-2,3-diyl)-based helically chiral phosphine ligands (PQXphos) with palladium(II) acetate afforded chiral phosphapalladacycles quantitatively. In situ generated palladacycles exhibited enantioselectivities up to 94 % ee in the palladium-catalyzed asymmetric ring-opening arylation of 1,4-epoxy-1,4-dihydronaphthalenes with arylboronic acids.

show abstract

An Overview of Polymer‐Immobilized Chiral Catalysts and Synthetic Chiral Polymers

Cited by 10 publications

References 114 publications

Solid-Phase Synthesis and Catalytic Screening of Polystyrene Supported Diphosphines

Solid-Phase Synthesis and Catalytic Screening of Polystyrene Supported Diphosphines

Chiral Palladacycle Catalysts Generated on a Single‐Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4‐Epoxy‐1,4‐dihydronaphthalene

Chiral Palladacycle Catalysts Generated on a Single‐Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4‐Epoxy‐1,4‐dihydronaphthalene

Contact Info

Product

Resources

About