An overview of catalytic conversion of CO2 into fuels and chemicals using metal organic frameworks

Mazari, Shaukat Ali; Hossain, Nazia; Basirun, Wan Jeffrey; Mubarak, Nabisab Mujawar; Abro, Rashid; Nizamuddin, Sabzoi; Shah, Asif Ali

doi:10.1016/j.psep.2020.10.025

Cited by 79 publications

(30 citation statements)

References 212 publications

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“…In the present decade, carbon dioxide utilization has reached around 110 million MT (metric tons) [18]. Carbon dioxide is also playing major role in the production of urea, [17] methanol [18], salicylic-acid [19], formic-acid [20], cyclic carbonates [21][22][23], copolymers, polymer building blocks, and fine chemicals [24][25][26][27]. Urea is one of the major fertilizers, and CO 2 is the source for it [26].…”

Section: Introductionmentioning

confidence: 99%

Review on Carbon Dioxide Utilization for Cycloaddition of Epoxides by Ionic Liquid-Modified Hybrid Catalysts: Effect of Influential Parameters and Mechanisms Insight

et al. 2020

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The storage, utilization, and control of the greenhouse (CO2) gas is a topic of interest for researchers in academia and society. The present review article is dedicating to cover the overall role of ionic liquid-modified hybrid materials in cycloaddition reactions. Special emphasis is on the synthesis of various cyclic carbonate using ionic liquid-based modified catalysts. Catalytic activity studies have discussed with respect to process conditions and their effects on conversion and product selectivity for the reaction of cycloaddition of CO2 with styrene oxide. The reaction temperature and the partial pressure of CO2 have found to play a key role in cyclic carbonate formation. The role of other influential parameter (solvent effect) is also discussed for the conversion of cyclic/aromatic oxides to polycarbonate production. Our own research work that deals with ionic liquid-based halide-modified mesoporous catalyst (MCM-41 type) derived from rice husk waste has also been discussed. Finally, the role of carbon dioxide activation and ring-opening mechanisms involved in the cyclic carbonate product formation from CO2 have been discussed.

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Section: Introductionmentioning

confidence: 99%

Review on Carbon Dioxide Utilization for Cycloaddition of Epoxides by Ionic Liquid-Modified Hybrid Catalysts: Effect of Influential Parameters and Mechanisms Insight

et al. 2020

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“…Thinner particle border--advanced is the value of dielectric constant. Upper dielectric constant (') matters noticed at lower frequencies are also elaborated on interfacial/space polarization because of inhomogeneous dielectric configuration [16,18].…”

Section: Dielectric Constantmentioning

confidence: 99%

“…To acquire materials with the desired physical and chemical properties, the preparation of ferrite nanoparticles through different routes has become an important area of research and development. Various methods of synthesizing spinel ferrite nanoparticles have been reported, such as ball milling, a ceramic process by firing [13], coprecipitation [14,15], reverse micelles [16], hydrothermal methods [17,18], a polymeric precursor [19], sol-gel [20], microemulsions [21], laser ablation [22], a polyol method [23], sonochemical approaches [24], and aerosol method [25]. Among these strategies, co-precipitation, as well as sol-gel, is usually renowned.…”

Section: Introductionmentioning

confidence: 99%

Fabrication & characterization of novel conductive nanomaterial, CaxCr0.5−xMg0.5Fe2O4

Nosheen

Iqbal

Bahadar

et al. 2021

Korean J. Chem. Eng.

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A novel conductive nano material, nano spinel ferrites having the composition of calcium chromium magnesium nanoferrites (Ca x Cr 0.5x Mg 0.5 Fe 2 O 4 ), was fabricated via sol-gel auto combustion process. The main objective was to fabricate highly stable nanocomposite as conductive material. Reaction among highly pure grade magnesium nitrate Mg (NO 3 ) 2 •6H 2 O, calcium nitrate Ca (NO 3 ) 2 •4H 2 O, and chromium nitrate Cr (NO 3 ) 3 •9H 2 O, ferric nitrate Fe (NO 3 ) 3 •9H 2 O took place to fabricate the desired material and, later on, an inductance (L)--capacitance (C)--resistance (R) meter (LCR meter) was used to determine the conductive behavior of the material. During characterization, thermogravimetric study confirmed that the stable phase was obtained above 950 o C. Fabricated ferrite FTIR spectrum was observed between 400 cm 1 and 4,500 cm 1 . The entire sample's structural investigation was carried out employing X-ray diffraction. Morphological analysis confirmed that particles possess angular structures having acute angles adjoining surfaces. During conductivity test, all fabricated nanoferrites presented that with the increase of frequency by LCR meter, AC conductivity had been increased. The outcome of doping of calcium on chromium magnesium nanoferrites on structural in addition to dielectric properties was synergistic.

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Section: Editorial On Research Topicmentioning

confidence: 99%

“…For example, converting CO 2 into polyols could enable the production of more sustainable elastomers, fibers, flexible foam, adhesives, sealants, inks, paints, and coatings. Another route that can be considered is the conversion of CO 2 in valuable energy carriers such as methane, methanol, etc., which could be an attractive CCU solution while simultaneously addressing global warming and storing of hydrogen energy or renewable energy in commonly used dense energy carriers [4][5][6]. However, for all the routes and targeted products, it is important to ensure that CCU pathways deliver the three following aspects: 1) sustainable cradle-tograve solutions 2) economically viable solutions 3) scalable solutions.In this Research Topic, we aimed to make a picture of the knowledge of the current progress in the area of CO 2 capture and conversion techniques.In particular, Skoricova et al proposed the techno-economic assessment of the sorptionenhanced dimethyl-ether (DME) synthesis process, as an innovative way for producing fuelgrade DME from carbon dioxide and green H 2 .…”

mentioning

confidence: 99%

Editorial: From CO2 Emissions to Fuels and Chemicals: Current Development, Challenges and Perspectives

Brunetti¹,

Roussanaly²,

Monteiro³

et al. 2021

Front. Chem. Eng.

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Editorial on Research TopicFrom CO 2 Emissions to Fuels and Chemicals: Current Development, Challenges and Perspectives Carbon capture and utilization (CCU) is attracting considerable attention as a new way to reduce release of greenhouse gases to the atmosphere while valorising CO 2 through the production of fuels and green chemical intermediates [1].Over the past decades, significant effort has been targeted at developing and demonstrating at large-scale CO 2 capture from power and industrial sources [2]. To accelerate deployment, further efforts are taking place to reduce energy penalties and costs of such a process, as well as scale-up promising solutions. However, one of the key hurdles for implementation remains the destination of these huge CO 2 streams. While CO 2 storage has been shown to be, by far, the main option to ensure permanent sequestration of the amount of CO 2 to be captured [3], integrating CO 2 capture and storage can be challenging, especially in the near term, due to the distances between sources and sinks, the time required to develop such geological sinks, scale mismatches, etc. While it is expected to play a smaller role than CO 2 storage, CO 2 utilization remains an interesting sink for captured CO 2 as it creates opportunities for new revenue streams. Furthermore, CO 2 utilization can also be considered for small capture flowrates which make it an interesting solution in the case of early deployment. There are many potential routes to convert CO 2 into useful and, hopefully, more sustainable chemicals and fuels. For example, converting CO 2 into polyols could enable the production of more sustainable elastomers, fibers, flexible foam, adhesives, sealants, inks, paints, and coatings. Another route that can be considered is the conversion of CO 2 in valuable energy carriers such as methane, methanol, etc., which could be an attractive CCU solution while simultaneously addressing global warming and storing of hydrogen energy or renewable energy in commonly used dense energy carriers [4][5][6]. However, for all the routes and targeted products, it is important to ensure that CCU pathways deliver the three following aspects: 1) sustainable cradle-tograve solutions 2) economically viable solutions 3) scalable solutions.In this Research Topic, we aimed to make a picture of the knowledge of the current progress in the area of CO 2 capture and conversion techniques.In particular, Skoricova et al. proposed the techno-economic assessment of the sorptionenhanced dimethyl-ether (DME) synthesis process, as an innovative way for producing fuelgrade DME from carbon dioxide and green H 2 . They found that the production cost for DME was ∼€1.3 per kg for a relatively small-scale production plant of 23 kt/year. Although higher than the current market price for fossil-based DME, the results showed the potential of this route as more

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An overview of catalytic conversion of CO2 into fuels and chemicals using metal organic frameworks

Cited by 79 publications

References 212 publications

Review on Carbon Dioxide Utilization for Cycloaddition of Epoxides by Ionic Liquid-Modified Hybrid Catalysts: Effect of Influential Parameters and Mechanisms Insight

Review on Carbon Dioxide Utilization for Cycloaddition of Epoxides by Ionic Liquid-Modified Hybrid Catalysts: Effect of Influential Parameters and Mechanisms Insight

Fabrication & characterization of novel conductive nanomaterial, CaxCr0.5−xMg0.5Fe2O4

Editorial: From CO2 Emissions to Fuels and Chemicals: Current Development, Challenges and Perspectives

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