Nanoporous silica aerogels have great potential in the
application
of thermal insulation. However, the commonly used supercritical drying
technology of nanoporous silica aerogels has disadvantages such as
high cost, high complexity, and harsh drying conditions. Herein, a
template orientation strategy has been proposed for fabricating nanoporous
aerogel-like silica monoliths (ASMs) based on the low-cost, rapid
ambient drying technology without additional treatments of surface
modification and solvent exchanging. The successful implementation
of the template orientation strategy depends on the silica slurry,
which is composed of commercial fumed silica, hydrolyzed methyltrimethoxysilane
(MTMS), and sole water solvent. The solidification of silica slurry
has been achieved by a controlled polycondensation reaction catalyzed
by ammonia originating from the thermolysis of urea. Owing to the
skeleton enhancement of fumed silica powders and the hydrophobic effect
of methyl groups, ASMs maintain well monolithic formability during
ambient drying. Meanwhile, low-cost fumed silica powders have been
seen as template orientation agents for inducing MTMS molecules to
generate nanoparticle-based network skeletons, endowing ASMs with
typical nanopore features (specific surface area as high as 113 m2/g and pore diameter distribution concentrated at ∼40
nm). The resulting ASMs exhibit low density (0.36 g/cm3), high compressive strength (0.92 MPa), and low thermal conductivity
[0.056 W/(m·K)]. This work would provide significant guidelines
for the fabrication and thermal insulation applications of nanoporous
ASMs derived from ceramic powders. This simple and low-cost preparation
strategy would promote the large-scale applications and industrial
production of nanoporous silica for thermal insulation materials.