An organified mixture of illite-kaolinite for the removal of Congo red from wastewater

Omer, Omer Sakin; Hussein, Belal H. M.; Ouf, A. M. A.; Hussein, Mohammed Ali; Mgaidi, Arbi

doi:10.1080/16583655.2018.1540179

Cited by 10 publications

(5 citation statements)

References 25 publications

(27 reference statements)

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“…The maximum CR adsorption capacity was: Pal (30.6 mg/g) > Pal-2M (22 mg/g) > Pal-4M (20.9 mg/g) ≈ Pal-6M (20 mg/g). The lower adsorption capacity of the palygorskite to the CR was attributed to the electrostatic repulsion between the negatively charged surface and the negative nature of the CR dye [92]. Furthermore, Yang et al [33] pointed out that the leaching of Mg 2+ and Ca 2+ ions decreases the zeta potential of palygorskite clay and reduces the anionic dyes' absorptive capacity.…”

Section: Resultsmentioning

confidence: 99%

Adsorption Behavior of Acid-Treated Brazilian Palygorskite for Cationic and Anionic Dyes Removal from the Water

et al. 2021

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The effect of acid treatment on the adsorptive capacity of a Brazilian palygorskite to remove the crystal violet (CV) and congo red (CR) dyes was investigated. The raw palygorskite was acid-treated by different HCl solutions (2, 4, and 6 mol/L). The modifications on the palygorskite structure were investigated using X-ray diffraction, X-ray fluorescence, Fourier-transform infrared spectroscopy, N2 adsorption/desorption, and thermogravimetric and differential thermal analysis. The efficiency of CV and CR adsorption was investigated, and the effect of the initial concentration, contact time, pH, and adsorbent amount was analyzed. The results revealed that CV adsorption in the acid-treated palygorskite was higher than that of the raw material. A Langmuir isotherm model was observed for the adsorption behavior of CV, while a Freundlich isotherm model was verified for the CR adsorption. A pseudo-second-order model was observed for the adsorption kinetics of both dyes. The higher CV adsorption capacity was observed at basic pH, higher than 97%, and the higher CR removal was observed at acidic pH, higher than 50%. The adsorption parameters of enthalpy (ΔH), entropy (ΔS), and Gibbs energy (ΔG) were evaluated. The adsorption process of the CV and CR dyes on the raw and acid-treated Brazilian palygorskite was predominantly endothermic and occurred spontaneously. The studied raw palygorskite has a mild-adsorption capacity to remove anionic dyes, while acid-treated samples effectively remove cationic dyes.

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Section: Resultsmentioning

confidence: 99%

Adsorption Behavior of Acid-Treated Brazilian Palygorskite for Cationic and Anionic Dyes Removal from the Water

et al. 2021

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“…In the present study, the experimental kinetic data for adsorption of CV and CR dyes on the CDA surface were analyzed using pseudo-first-order, 56 pseudo-second-order, 57 and intraparticle diffusion 58 models, which are expressed according to the following equations: …”

Section: Methodsmentioning

confidence: 99%

Eco-Efficient Green Seaweed Codium decorticatum Biosorbent for Textile Dyes: Characterization, Mechanism, Recyclability, and RSM Optimization

et al. 2020

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Biosorption using natural waste has emerged as a potential and promising strategy for removal of toxic dyes from wastewaters in comparison to conventional ones. Herein, the Codium decorticatum alga (CDA) was biologically identified and used as a biosorbent for anionic and cationic dyes from aqueous solutions. SEM analysis showed a rough surface with an irregular edge and shape while hydroxyl, amine, sulfur and carboxyl functional groups were identified using FTIR analysis. TGA/DTG confirmed the stability of CDA and the adsorption process. Batch studies were conducted to investigate the effect of operational factors such as initial pH, biosorbent dosage, temperature, initial concentration, and solid/liquid contact time on the biosorption of crystal violet (CV) and Congo red (CR) dyes. For both CV and CR dyes, the biosorption kinetics was accurately described by the pseudo-second-order model and the Langmuir isotherm was found to be best fitted for equilibrium data. Maximum uptake capacities have attained up to 278.46 mg/g for CV and 191.01 mg/g for CR. The CV and CR dye biosorption mechanism was ultimately manifested through the electrostatic interactions. The regeneration study showed that the CDA presents excellent reuse performance up to four consecutive cycles. The process optimization was performed using the response surface methodology based on Box–Behnken design (RSM-BDD). Accordingly, the optimum predicted removal efficiencies using RSM-BBD for CV and CR were obtained, respectively, at 96.9 and 89.8% using a CDA dose of 1.5 g/L, dye concentration of 20 mg/L, pH of 10 for CV, and pH of 4 for CR. Overall, CDA behaves as an efficient, recyclable, cheap, and eco-friendly adsorbent for cleaning-up of dyed effluents.

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“…Additionally, the sorption-desorption hysteresis clearly shows that liquid nitrogen is condensed in the mesopores of used material (GCM). The limited absorption over a range of high P/P0 and capillary condensation occurring in mesopores are the causes of the observed hysteresis (Omer et al, 2018;Dinh et al, 2022). The IUPAC classification allows the hysteresis to be categorized as type H2 (Kgabi and Ambushe, 2023).…”

Section: Bet Analysismentioning

confidence: 99%

Green clay materials applied in packed bed columns for adsorption of hexavalent chromium from aqueous solutions

Eloussaief,

Dammak,

Ghrab

et al. 2024

Preprint

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The removal of hazardous metal ions from polluted water is a crucial process aimed at enhancing water quality. In this study, we conducted a dynamic adsorption investigation utilizing natural green clay for the removal of hexavalent chromium from aqueous solutions. The material underwent characterization through various techniques, including fluorescence spectrometry (XRF), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and nitrogen-physisorption (BET). Column tests of green clay material and sand mixtures were performed to evaluate sorption in dynamic systems. Adsorption conditions were examined by varying the initial Cr6+ concentration, flow rate and column height. The maximum purification was achieved at a concentration of 50 mg/L, a flow rate of 3mL/min and a bed height of 12 cm. The mathematical models of Bohart-Adams, Thomas, and Yoon-Nelson were employed to analyze experimental data and predict breakthrough curves in continuous adsorption. Through comparison of R2 values, it was determined that the Yoon-Nelson and Thomas diffusion models effectively capture and accurately describe the experimental data. The results obtained indicate a potential expansion of fixed-bed adsorption for the heavy metals treatment in industrial-scale wastewater. Additionally, the natural green clay material exhibited remarkable reusability and showed promising characteristics for various environmental and industrial applications.

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An organified mixture of illite-kaolinite for the removal of Congo red from wastewater

Cited by 10 publications

References 25 publications

Adsorption Behavior of Acid-Treated Brazilian Palygorskite for Cationic and Anionic Dyes Removal from the Water

Adsorption Behavior of Acid-Treated Brazilian Palygorskite for Cationic and Anionic Dyes Removal from the Water

Eco-Efficient Green Seaweed Codium decorticatum Biosorbent for Textile Dyes: Characterization, Mechanism, Recyclability, and RSM Optimization

Green clay materials applied in packed bed columns for adsorption of hexavalent chromium from aqueous solutions

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