An optical sensing platform for the dual channel detection of picric acid: The combination of rhodamine and metal-organic frameworks

Gao, Yuqian; Qi, Yuancheng; Zhao, Kui; Wen, Qing; Shen, Jinwen; Qiu, Liyou; Mou, Wanzhi

doi:10.1016/j.snb.2017.11.007

Cited by 33 publications

(10 citation statements)

References 22 publications

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“…In recent years, nitroaromatic compounds (NACs) have attracted intensive attention in environmental cleaning, national security and military . Especially, 2,4,6‐Trinitrophenol (picric acid, PA) is an explosive material with a higher power than 2,4,6‐trinitrotoluene (TNT), which is widely used in fireworks, dyes, explosives, pharmaceuticals . It should be noted that PA has extremely high toxicity and it can cause severe health problems, such as contact dermatitis, conjunctivitis and bronchitis .…”

Section: Introductionmentioning

confidence: 99%

Fluorene‐based Lanthanide Coordination Polymer: Structure, Luminescence and Sensing of Picric Acid

Cheng

Liu

Wang

et al. 2019

Applied Organom Chemis

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Luminescent coordination polymers can be potential chemosensors and extensive efforts are being devoted to improve their selectivity and sensitivity. In this work, we report a new kind of fluorene-based Tb-CP, Tb 4 L 6 ·7DMF·5H 2 O (Tb 4 L 6 , H 2 L = 4,4′-(9,9-dimethyl-9H-fluorene-2,7-diyl)dibenzoic acid), showing 2D network and strong blue emission. Meanwhile, Tb 4 L 6 exhibits excellent selectivity and sensitivity for picric acid (PA). The quenching constant (K sv ) of Tb 4 L 6 is equal to 4.5 × 10 4 L/mol during the concentration range of 0-30 μmol/L, which approaches the best reported CPs-based on PA sensor up to now. Moreover, we went into depth on the possible mechanisms of luminescence quenching.

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Section: Introductionmentioning

confidence: 99%

Fluorene‐based Lanthanide Coordination Polymer: Structure, Luminescence and Sensing of Picric Acid

Cheng

Liu

Wang

et al. 2019

Applied Organom Chemis

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“…FRET should be directly correlated with the steric hindrance between the acceptor and donor; when the steric hindrance becomes higher, the FRET transfer property may become worse. 46 According to the above-mentioned analysis, the sensing mechanism for RhB@MOF1 toward lysine should be ascribed to the coefficient effect of FRET.…”

Section: Sensing Mechanism For Rhb@mof1 Towardmentioning

confidence: 99%

Hydrothermal Preparation of Five Rare-Earth (Re = Dy, Gd, Ho, Pr, and Sm) Luminescent Cluster-Based Coordination Materials: The First MOFs-based Ratiometric Fluorescent Sensor for Lysine and Bifunctional Sensing Platform for Insulin and Al³⁺

Wang

Huang

et al. 2018

Inorg. Chem.

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Through the powerful hydrothermal method, five rare-earth (Re = Dy, Gd, Ho, Pr, and Sm) three-dimensional (3D) cluster-based metal–organic frameworks (MOFs) have been synthesized, namely, [Dy(L)(H2O)(DMF)] n (1), {[Gd(L)(H2O)(DMF)]·DMF} n (2), {[Ho(L)(H2O)(DMF)]·0.5DMF} n (3), {[Pr(L)(H2O)(DMF)]·0.5DMF} n (4), and {[Sm(L)(H2O)1.55(DMF)0.45]·DMF} n (5; H3L = terphenyl-3,4″,5-tricarboxylic acid), which have been determined by single crystal X-ray analyses and PXRD characterization. Structural analyses reveal that, in 1–5, these L3– ligands are linked by five different rare-earth centers, forming the iso-structural nanoporous frameworks. PXRD patterns of bulky samples 1–5 also are consistent with theoretical PXRD patterns confirming their purity. Solid state photoluminesce of free H3L and 1–5 at room temperature also has been investigated indicating strong ligand-based emissions. Besides these, fluorescent dye Rhodamine B (RhB) can be introduced into MOF1 forming the composite material RhB@MOF1 with a high quantum yield of 35%. It is noted that, through deliberately tuning the morphologies of nanoparticle MOF1 under different ultrasonic conditions, RhB@MOF1 can be utilized as the first ratiometric fluorescent sensor to effectively discriminate l- and d-lysine from other amino acid molecules with high K sv values and low LOD values. On the other hand, 2 was for the first time to be utilized as an excellent bifunctional MOFs-based sensing platform to detect insulin and Al3+ with a low detection limit in the human serum solution.

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“…Also, TNP is the most acidic member of phenolic NACs in the order of TNP (p K a = 0.4), 2,4-dinitrophenol (DNP, p K a = 4.0), 4-nitrophenol (PNP, p K a = 7.16), and 2-nitrophenol (ONP, p K a = 7.24). , Moreover, TNP is a photoactive molecule and has a relatively strong absorption band at 300–450 nm. Investigations of published papers on the detection of TNP by MOFs have determined that in the many cases with selectivity tests, that between a TNP molecule and −NH 2 -substituted NACs (as serious interferers) was not explored ,− ,,,,− or poor selectivity was obtained when the TNP detection is investigated along with −NH 2 -substituted NACs. ,− A review of the literature shows that only rare examples have been successful in obtaining high TNP selectivity in the presence of −NH 2 -substituted NACs. ,,, These surprising and complex challenges in the selective detection of a specific group of substituted NACs, especially TNP, inspired us to investigate a way to solve this challenge using functional MOFs with optimized host–guest chemistry.…”

Section: Introductionmentioning

confidence: 99%

A Dihydrotetrazine-Functionalized Metal–Organic Framework as a Highly Selective Luminescent Host–Guest Sensor for Detection of 2,4,6-Trinitrophenol

2022

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Pore decoration of metal−organic frameworks (MOFs) with functional groups is a useful strategy to attain high selectivity toward specific analytes, especially in the presence of interfering molecules with similar structures and energy levels, through selective host−guest interactions. In this work, we applied a dihydrotetrazine-decorated MOF, TMU-34, with the formula [Zn(OBA)(H 2 DPT) 0.5 ] n •DMF, where H 2 OBA is 4,4′-oxybis-(benzoic acid) and H 2 DPT is 3,6-bis(pyridin-4-yl)-1,4-dihydro-1,2,4,5-tetrazine, for the highly selective detection of phenolic NACs, especially TNP (94% quenching efficiency, detection limit 8.1 × 10 −6 M, K SV = 182663 mol L −1 ), in the presence of other substituted NACs especially −NH 2 -substituted NACs. Investigations reveal that the quenching mechanism is dominated by photoinduced MOF-to-TNP electron transfer through possible hydrogen-bonding interactions between the phenolic hydroxyl group of TNP and dihydrotetrazine functions of TMU-34. Despite extensive publications on the detection of TNP in the presence of other NACs, the significance of this work will be elucidated if attention is paid to the fact that TMU-34 is among the rare and highly selective MOF-based TNP sensors in the presence of −NH 2 -substituted NACs as the serious interferers.

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An optical sensing platform for the dual channel detection of picric acid: The combination of rhodamine and metal-organic frameworks

Cited by 33 publications

References 22 publications

Fluorene‐based Lanthanide Coordination Polymer: Structure, Luminescence and Sensing of Picric Acid

Fluorene‐based Lanthanide Coordination Polymer: Structure, Luminescence and Sensing of Picric Acid

Hydrothermal Preparation of Five Rare-Earth (Re = Dy, Gd, Ho, Pr, and Sm) Luminescent Cluster-Based Coordination Materials: The First MOFs-based Ratiometric Fluorescent Sensor for Lysine and Bifunctional Sensing Platform for Insulin and Al³⁺

A Dihydrotetrazine-Functionalized Metal–Organic Framework as a Highly Selective Luminescent Host–Guest Sensor for Detection of 2,4,6-Trinitrophenol

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An optical sensing platform for the dual channel detection of picric acid: The combination of rhodamine and metal-organic frameworks

Cited by 33 publications

References 22 publications

Fluorene‐based Lanthanide Coordination Polymer: Structure, Luminescence and Sensing of Picric Acid

Fluorene‐based Lanthanide Coordination Polymer: Structure, Luminescence and Sensing of Picric Acid

Hydrothermal Preparation of Five Rare-Earth (Re = Dy, Gd, Ho, Pr, and Sm) Luminescent Cluster-Based Coordination Materials: The First MOFs-based Ratiometric Fluorescent Sensor for Lysine and Bifunctional Sensing Platform for Insulin and Al3+

A Dihydrotetrazine-Functionalized Metal–Organic Framework as a Highly Selective Luminescent Host–Guest Sensor for Detection of 2,4,6-Trinitrophenol

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Hydrothermal Preparation of Five Rare-Earth (Re = Dy, Gd, Ho, Pr, and Sm) Luminescent Cluster-Based Coordination Materials: The First MOFs-based Ratiometric Fluorescent Sensor for Lysine and Bifunctional Sensing Platform for Insulin and Al³⁺