The Otele, Matomb and Nguibassal localities correspond to the SW part of the Yaoundé Group. Field observations, rocks and stream sediments of the study area were examined using rock tin sections, granulometric, morphoscopic and X-ray fluorescence analysis to identify their distribution, the nature of the basement, provenance useful minerals and some weathering process that affect them to show the exploration significance of these outcomes. From these it appears that, three rocks types occur in the areas: gneisses, micaschists and amphibolite, respectively with the following minerals assemblage: (Fks + Bt + Qz + Ky + Pl + Msc + Grt + Op), (Bt + Qz + Msc + Fks + Op + Ky + Grt) and (Amp + Bt + Pl + Kfs + Qz + Px + Grt + Op). Sedimentological analyses reveal the dominance of unworn grains of rutile quartz and kyanite that suggest a short transport; while less abundant minor shiny dulls and sub-rounded grains suggest a long transport. Sediments collected are homometric, well sorted, well classified, with immature rutile due to their angular shapes. Silica is the most important major element ranging in concentration between 47.56 wt% SiO 2 in amphibolite to 61.21 wt% SiO 2 in gneiss. Stream sediments chemistry equally showed that silica and alumina are the remarkable elements with values of 53.92 wt% and 13.33 wt% respectively with important increase of TiO 2 ranging between 51.77 and 95.03 wt%. The TiO 2 percentage met in minerals of the global fraction and rutile concentrate come from the same minerals in the rock, and percentage increases when linked to heavy minerals observation suggested the Ti percentage to mainly come from rutile.