An insight into non-covalent interactions in the tetraphenylarsonium dithiophosphates: Synthesis, DFT and Hirshfeld surface analysis

Thallium(i)phosphorodithioates containing intra- and intermolecular π-hole triel bonds

“…The present investigation is an extension of our ongoing research interest in non-covalent interactions. 40–46 We herein designed and characterized two new diaryldithiophosphato- S , S ′-thallium compounds, corresponding to Tl + [S 2 P{OC 6 H 3 (2,5-(CH 3 ) 2 )} 2 ] − ( 1 ) and Tl + [S 2 P{OC 6 H 3 (3,5-(CH 3 ) 2 )} 2 ] − ( 2 ), consisting of a π-hole at the Tl atom, which results in Tl–C/S triel bonds. In this study, we placed particular focus on the self-assembled structures formed by Tl( i )⋯S, Tl( i )⋯C TrBs, anagostic, and other non-covalent interactions.…”

“…17, The present investigation is an extension of our ongoing research interest in non-covalent interactions. [40][41][42][43][44][45][46] We herein designed and characterized two new diaryldithiophosphato-S, S′-thallium compounds, corresponding to Tl + [S 2 P{OC 6 H 3 (2,5-…”

The Hirshfeld Surface Analysis of Antimony(III) and Bismuth(III) Complexes with Dithiocarbamate Ligands

“…Hirshfeld surfaces mapped with dnorm visually present significant intermolecular interactions between atoms in compounds with red dots. Two-dimensional fingerprints provide information about the contributions of non-covalent interactions to the hirshfeld surfaces [10]. (8), and {[BiI(Et2DTC)2]n} (9), previously synthesized and characterized in the literature, were selected [11][12][13][14] .…”