An improved method for the synthesis and formation mechanism of M2B10H14 based on the reactions of B10H14 with MNH2BH3 (M = Na, K)

Chen, Xi-Meng; Yu, Xing-Chao; Chi, Jing-Xian; Jing, Yi; Wang, Hongju; Zhang, Na; Zhang, Chen; Ge, Yi-Wen; Chen, Xuenian

doi:10.1039/d3dt03403h

Dalton Trans.

2023

DOI: 10.1039/d3dt03403h

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An improved method for the synthesis and formation mechanism of M₂B₁₀H₁₄ based on the reactions of B₁₀H₁₄ with MNH₂BH₃ (M = Na, K)

Xi-Meng Chen,

Xing-Chao Yu,

Jing-Xian Chi

et al.

Abstract: An improved method for the synthesis of M2B10H14 (M = Na and K) has been developed, and two possible formation mechanisms of the B10H142− anion were proposed, in which the NH2BH3− anion acts as a proton abstractor and a hydride donor.

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An improved method for the synthesis and formation mechanism of M₂B₁₀H₁₄ based on the reactions of B₁₀H₁₄ with MNH₂BH₃ (M = Na, K)

Abstract: An improved method for the synthesis of M2B10H14 (M = Na and K) has been developed, and two possible formation mechanisms of the B10H142− anion were proposed, in which the NH2BH3− anion acts as a proton abstractor and a hydride donor.

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References 46 publications

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