Abstract.Estimates of the rate of production of excited oxygen atoms due to the photolysis of ozone (J (O 1 D)) have been derived from radiation measurements carried out at Cape Grim, Tasmania (40.6 • S, 144.7 • E). The individual measurements have a total uncertainty of 16 % (1σ ). These estimates agree well with model estimates of clear-sky photolysis rates. Observations spanning 2000-2005 have been used to quantify the impact of season, clouds and ozone column amount. The annual cycle of J (O 1 D) has been investigated via monthly means. These means show an interannual variation (monthly standard deviation) of 9 %, but in midsummer and midwinter this reduces to 3-5 %. Variations in solar zenith angle and total column ozone explain 86 % of the observed variability in the measured photolysis rates. The impact of total column ozone, expressed as a radiation amplification factor (RAF), is found to be ∼ 1.53, in agreement with model estimates. This ozone dependence explains 20 % of the variation observed at medium solar zenith angles (30-50 • ). The impact of clouds results in a median reduction of 30 % in J (O 1 D) for the same solar zenith angle range. Including estimates of cloudiness derived from long-wave radiation measurements resulted in a statistically significant fit to observations, but the quality of the fit did not increase significantly as measured by the adjusted R 2 .