An FT-IR and TGA Study of the Thermal Oxidation of C60

Abstract

The thermal stability of C60 in pure oxygen has been investigated by in-situ FT-IR and thermogravimetric analysis (TGA). It is shown that at temperatures of about 250 °C, the C60 loses its spherically symmetric structure and is oxidized to an anhydride type species. The anhydride on exposure to air is converted to an acid which however reverts to the anhydride on heating in a nitrogen or oxygen atmosphere. On heating beyond 250 °C, the C60 is completely oxidized probably to CO and CO2, but this complete oxidation appears to take place in two stages with the anhydride part of the molecule getting oxidized first. It is postulated that the lower oxidative stability of C60 compared to graphite is probably due to the greater reactivity towards oxygen of the pentagon–hexagon junction, compared to the hexagon–hexagon junction, present in C60.

Transformation of Aggregated C60 in the Aqueous Phase by UV Irradiation

“…If transformation occurs, products may have very different fate(s) in the environment and may also have different toxicological effects. Compared to abundant reports of reactivity of C 60 in organic solvents ,− ,,, , little is known regarding reactions of C 60 (as nC 60 ) in the aqueous phase. A recent study by Fortner et al demonstrated that nC 60 can be transformed into highly oxygenated, molecularly soluble products upon reaction with dissolved ozone.…”