In
comparison to the continuous breakthrough in shale gas of marine
basins, the pace of study of lacustrine basins is relatively slow.
The latest studies have shown the saline lacustrine rifting basins
(SLRBs) are one of the favorable exploration areas from the view of
shale pore, mineral composition, and organic matter accumulation.
However, the study on the gas generation potential and characteristics
is still lacking because the traditional view is that lacustrine source
rocks are oil-prone. Therefore, to identify gas generation potential
and characteristics of oil-prone shale in SLRBs, the samples from
the saline area (SA) and non-saline area (NA) of the Dongpu Depression
are selected for the organic geochemical experiments and closed gold
cube thermal simulation experiments. Geochemical results show that
the SA samples are definitely oil-prone source rocks with high quality,
and their main type is II kerogen. However, the results from thermal
simulation experiments indicate that the gas generation potential
of oil-prone shale in SLRBs is enough for the accumulation of shale
gas with the peak gas yield of 469.11 mg/g of TOC at the heating rate
of 20 °C/h TOC and 466.75 mg/g of TOC at the heating rate of
2 °C/h and TOC. Moreover, according to the dynamic hydrocarbon
yields and carbon isotope (ln C2/C3, ln C1/C2, and δ13C1–δ13C2) during the increasing temperature, the gas
generation process for SA and NA samples can be divided into three
stages: kerogen cracking, oil cracking, and wet gas cracking. In comparison
to other types of source rocks (marine shale, coal, and coal mudstone),
the SA oil-prone shale can experience longer intervals in kerogen
cracking and oil cracking, which may be the main stage of gas generation.
The model based on kinetic parameters shows that the main gas generation
period for SA and NA samples is the late Es1 (the first
member of Shahejie Formation) to Ed (the Dongying Formation) of the
Early Cenozoic, which can be consist of the depression stage with
the deepest depth and the largest subsidence amplitude in the Dongpu
Depression. Such information can be a reference for other SLRBs.