An evaluation of the enhanced oil recovery potential of the xanthan gum and aquagel in a heavy oil reservoir in Trinidad

Abstract

The economy of Trinidad and Tobago which mainly relies on its energy sector is facing significant challenges due to declining crude oil production in a low commodity price environment. The need for enhanced oil recovery (EOR) methods to meet the current and future energy demands is urgent. Studies on the use of polymer flooding in Trinidad and Tobago are limited, especially in terms of necessary data concerning the characterization of the adsorption of polymer flooding chemicals such as xanthan gum and aquagel polymers on different soil types in Trinidad and the viscosity characteristics of the polymer flooding solutions which affect the key attributes of displacement and sweep efficiency that are needed to predict recovery efficiency and the potential use of these flooding agents in a particular well. Adsorption and viscosity experiments were conducted using xanthan gum and aquagel on three different soil types, namely sand, Valencia clay (high iron) and Longdenville clay (low iron). Xanthan gum exhibited the lowest adsorption capacity for Valencia clay but absorbed most on sand at concentrations above 1000 ppm and Longdenville clay below 1000 ppm. At concentrations below 250 ppm, all three soil-type absorbent materials exhibited similar adsorption capacities. Aquagel was more significantly absorbed on the three soil types compared to xanthan gum. The lowest adsorption capacity was observed for Valencia clay at concentration levels above 500 ppm; however, the clay had the highest adsorption capacity below this level. Sand had the highest adsorption capacity for aquagel at concentrations above 500 ppm while Longdenville clay was the lowest absorbent above 500 ppm. Generally, all three soil types had a similar adsorption capacity for xanthan gum at a concentration level of 250 ppm and for aquagel at a concentration level of 500 ppm. The results offered conclusive evidence demonstrating the importance that the pore structure characteristics of soil that may be present in oil wells on its adsorption characteristics and efficiency. Xanthan gum polymer concentration of 2000 ppm, 1000 ppm and 250 ppm showed viscosities of 125 cp, 63 cp and 42 cp, respectively. Aquagel polymer concentrations of 2000 ppm, 1000 ppm and 250 ppm showed viscosities of 63 cp, 42 cp and 21 cp, respectively. Aquagel polymer solutions were found to generally have lower viscosities than the xanthan gum polymer solutions at the same concentration. Adsorption and viscosity data for the xanthan gum and aquagel polymers were incorporated within CMG numerical simulation models to determine the technical feasibility of implementing a polymer flood in the selected EOR 44 located in the Oropouche field in the southwest peninsula of the island of Trinidad. Overall, aquagel polymer flood resulted in a higher oil recovery of 0.06 STB compared to the xanthan gum polymer flood, so the better EOR method would be aquagel polymer flood. Additionally, both cases of polymer flooding resulted in higher levels of oil recovery compared to CO 2 injection and waterfloo...

Evaluation of an alkali-polymer flooding technique for enhanced oil recovery in Trinidad and Tobago

“…The adsorption study was conducted according to Coolman et al (2020). Working polymer solutions of concentrations of xanthan gum polymers (500 ppm, 1000 ppm, 2000 ppm and 4000 ppm) representing typical dosages used in industry were mixed in various NaOH solutions at concentrations (0.25%, 0.5%.…”

“…As described by Coolman et al (2020), the viscosities of the 500 ppm, 1000 ppm, 2000 ppm and 4000 ppm concentrations of xanthan gum polymer solutions at the various pH values were analysed using an OFITE Testing 8-speed Rotational viscometer. Measurements of viscosities were recorded for shear rates from 6 to 600 rpm.…”

“…In TT, a recent study conducted by Coolman et al (2020) investigated the adsorption and viscosity characteristics of the polymer flooding additives xanthan gum and Aquagel on three different soil types, namely sand, Valencia clay (high iron) and Longdenville clay (low iron). The results offered conclusive evidence demonstrating the critical importance of the soil type and the pore structure characteristics of the soil that may be present in oil wells as it relates to the adsorption characteristics of the polymer flooding agents.…”

Evaluating rheological properties and recovery performance of polymeric anionic surfactant (PSURFC) synthesized from non-edible seed oil on heavy crude recovery

“…Polymer flooding appears as a good alternative method to reduce water production by improving immobility thereby achieving better-swept efficiency (Agrawal and Satapathy 2019). In sandstone reservoirs, the application of polymer flooding already proved to be an important enhanced oil recovery method because it has improved sweep efficiency when added to water (Coolman and Alexander 2020). In addition, the most polymer flooding exhibits low interfacial tension with regard to the oil phase, provides complete solubility and good mobility control (Al-Manasir and Kjøniksen 2009).…”

“…However, several categories of polymers (water soluble) have been reviewed and are commonly classified into two categories: synthetic and biopolymer. One of non-ionic biopolymers is Xanthan gum it have been effectively applied in the oil recovery as a recovery agent and drilling mud (Coolman and Alexander 2020).…”