An ESIPT based turn on fluorochromogenic sensor for low level discrimination of chemically analogous Zn2+ and Cd2+ & aqueous phase recognition of bio-hazardous CN-: From solution state analysis to prototype fabrication
“…Benzothiadiazole has strong electron-withdrawing ability, while diphenylamine has strong electrondonating ability, these donor-acceptor (DÀ A) structures facilitated near-infrared (NIR) emission. The chemical structures were characterized by 1 H-NMR, 13 C-NMR, and MS (MALDI-TOF) and satisfactory results obtained (Figures S1-S6). According to 1 H-NMR spectra, the singlet peak at ∼ 9.43 ppm was attributed to the characteristic proton resonance from NÀ H in DPCN.…”
Two novel benzothiadiazole derivatives were prepared. Clear color changes from orange‐red to blue (DPCN) and pink to green (DPTPE) were observed after the addition of fluoride ions (F−). DPCN and DPTPE displayed ratiometric fluorescence changes in the presence of F−. 1H‐NMR titration and DFT calculations confirmed deprotonation in the presence of F−. Compared with DPTPE, the hydrogen proton of the imine group in DPCN had higher activity due to the influence of the strong electron‐withdrawing cyano group, such that it was more easily deprotonated and the detection limit for F− was much lower. This work provided guidance for the further design and preparation benzothiadiazole based colorimetric and ratiometric fluorescence sensor for F−.
“…Benzothiadiazole has strong electron-withdrawing ability, while diphenylamine has strong electrondonating ability, these donor-acceptor (DÀ A) structures facilitated near-infrared (NIR) emission. The chemical structures were characterized by 1 H-NMR, 13 C-NMR, and MS (MALDI-TOF) and satisfactory results obtained (Figures S1-S6). According to 1 H-NMR spectra, the singlet peak at ∼ 9.43 ppm was attributed to the characteristic proton resonance from NÀ H in DPCN.…”
Two novel benzothiadiazole derivatives were prepared. Clear color changes from orange‐red to blue (DPCN) and pink to green (DPTPE) were observed after the addition of fluoride ions (F−). DPCN and DPTPE displayed ratiometric fluorescence changes in the presence of F−. 1H‐NMR titration and DFT calculations confirmed deprotonation in the presence of F−. Compared with DPTPE, the hydrogen proton of the imine group in DPCN had higher activity due to the influence of the strong electron‐withdrawing cyano group, such that it was more easily deprotonated and the detection limit for F− was much lower. This work provided guidance for the further design and preparation benzothiadiazole based colorimetric and ratiometric fluorescence sensor for F−.
“…The reliability of the present method was been verified using a UV-Vis spectrophotometer. 110 Banerjee et al 111 unveiled the versatile naphthalenebenzothiazole-based probe 78, which displayed the selective dual-channel colorimetric and fluorometric detection of aqueous CN À among a pool of other anions. The sensing mechanism was rationalized by ICT and the intermolecular H-bonding interaction pathway, which was well established by combined experimental and theoretical analysis.…”
Section: Interfacing Of Chemistry With Molecular Electronics Via Abri...mentioning
Copper is an indispensable transition element owing to its significant physiological activities. However, an unregulated overloading of this biologically ubiquitous ion can induce severe neurodegenerative diseases. Likewise, amidst the anions,...
“…9 ). 51 The donor part such as –C N enhances the reliability of the sensor, and the active functional group such as –OH improves the color detection efficiency of the sensor for the target analyte. Sensor 26 (1 × 10 −5 M, CH 3 CN) can recognize Cd 2+ in pure water by turning on fluorescence.…”
Section: Benzothiazole Based CD
2+
Fluorescent Sensormentioning
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