“…The u-functionality of the polymer chain is then exploited for the preparation of surface-tethered redox polymer brushes on the surface of electrochemical quartz crystal microbalance (EQCM) sensors. Besides quantifying the mass loading of surface-attached polymers, [22][23][24] EQCM technique is also exploited to study the electrochemical behavior of redox active polymer brush.…”
mentioning
confidence: 99%
“…The high frequency shi (Df 7 ¼ 611.1 Hz) that was monitored aer deposition and thermal activation of 4 indicated the formation of an adherent polymer layer because it was not removed aer intensive rinsing. According to the Sauerbrey equation, 24,34 the calculated chemisorbed amount of redox polymer was 10.71 mg.cm À2 .…”
A new strategy for the synthesis of a well-defined redox active polymer, a polyacrylate bearing TEMPO, and its grafting onto a gold substrate is described.
“…The u-functionality of the polymer chain is then exploited for the preparation of surface-tethered redox polymer brushes on the surface of electrochemical quartz crystal microbalance (EQCM) sensors. Besides quantifying the mass loading of surface-attached polymers, [22][23][24] EQCM technique is also exploited to study the electrochemical behavior of redox active polymer brush.…”
mentioning
confidence: 99%
“…The high frequency shi (Df 7 ¼ 611.1 Hz) that was monitored aer deposition and thermal activation of 4 indicated the formation of an adherent polymer layer because it was not removed aer intensive rinsing. According to the Sauerbrey equation, 24,34 the calculated chemisorbed amount of redox polymer was 10.71 mg.cm À2 .…”
A new strategy for the synthesis of a well-defined redox active polymer, a polyacrylate bearing TEMPO, and its grafting onto a gold substrate is described.
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