“…These materials were first introduced as calcium-free inorganic cements by Davidovits in 1978 4 and since then they have been attracting increasing attention due to their promising characteristics. They have been mainly proposed as more environmentally friendly substitutes of Portland cement 5,6 because of the greater energy efficiency of their manufacturing process and the substantial reduction in CO 2 emissions 7,8 . Following the particular aluminosilicate precursor 3 , the stoichiometric ratio of Si/Al [1,9] , alkali hydroxide and water content 10,11 as well as the reaction temperature, pressure 3 , activation, setting and curing procedures 11,12 , geopolymers can exhibit a wide variety of properties, such as high compressive strength, low shrinkage, fast or slow setting, acid and fire resistance, low thermal conductivity, long term durability and thermal stability.…”