Top-gate
self-aligned structured oxide thin-film transistors (TFTs)
are suitable for the backplanes of high-end displays because of their
low parasitic capacitances. The gate insulator (GI) deposition process
should be carefully designed to manufacture a highly stable, high-mobility
oxide TFT, particularly for a top-gate structure. In this study, a
nanometer-thick Al2O3 layer via plasma-enhanced
atomic layer deposition (PE-ALD) is deposited on the top-gate bottom-contact
structured oxide TFT as the interface tailoring layer, which can also
act as the hydrogen barrier to modulate carrier generation from hydrogen
incorporation into the active layer of the TFT during the following
process such as postannealing. Al-doped InSnZnO (Al/ITZO) with an
Al/In/Sn/Zn atomic ratio composition of 1.7:24.3:40:34 was used for
high mobility oxide semiconductors, and an Al2O3/Si3N4 bilayer was used for the GI. The degradation
issue due to the excellent barrier characteristics of Al2O3 and Si3N4 can be minimized. An
oxide TFT fabricated without the interface tailoring layer exhibits
conductor-like characteristics owing to the excessive carrier generation
by hydrogen incorporation. However, TFTs with additional interface
layers exhibit reasonable characteristics and distinct trends in electrical
characteristics depending on the thicknesses of the interface layers.
The optimized devices exhibit an average turn-on voltage (V
on) of −0.31 V with 33.63 cm2/(V s) of high mobility and 0.09 V/dec of subthreshold swing value.
The interfaces between the active layer and hydrogen barriers were
investigated using a high-resolution transmission electron microscope,
contact angle measurement, and secondary ion mass spectroscopy to
reveal the origin of the trends in properties between the devices.
The top-gate device with a hydrogen barrier using the four-cycle deposition
exhibits optimum electrical characteristics of both high mobility
and good stability with only a 0.04 V shift of V
on under positive-bias temperature stress (PBTS). We realize
a high-end, self-aligned TFT with high mobility [34.7 cm2/(V s)] and negligible V
on shift of −0.06
V under PBTS by applying a subnanometer hydrogen barrier.