“…First, high volume ratio of Pd-Ni/SiNW electrode increases the activity surface, accelerating the electron-transfer reaction, lowering the activation energy. Second, after annealed at 350 • C for 300 s, the Ni-Si layer located between the Ni and silicon nanowire (SiNW) interface has been formed, which prevents the electrode from etching by OH − ions and improves the electrode stability [20,26]. Third, the Pd-Ni particles are deposited onto the SiNWs with high uniformity and good dispersion, indicating that a large amount of Pd-Ni nanoparticles participate in the reaction and result in high activity.…”