Abstract-In this paper, a novel W-band substrate integrated waveguide (SIW) power combiner/divider is analyzed theoretically and demonstrated experimentally/numerically, based on the antipodal fin-line SIW-rectangular waveguide (SIW-RW) transition and longitudinal slot coupling techniques. This antipodal fin-line SIW-RW transition can work at the frequency band of 86.4 GHz-106.1 GHz with return loss larger than 15 dB and inserting loss less than 2 dB. By combining the antipodal fin-line SIW-RW into the four-way longitudinal-slot SIW coupling structure, a novel back-to-back power dividing/combining system is achieved, which can operate at the frequency band of 92.8 GHz-93.8 GHz with return loss more than 10 dB and insertion loss less than 3.9 dB. Such a design can be used in future for spatial power amplifier applications.