An Efficient Magnesium Phyllosilicate‐Nano Palladium Hybrid Catalyst for the Selective Oxidation of Organosilanes

Santhini, P. V.; Das, Gourab; Mole, Julie; Kumar, Abhijith S.; Vedhanarayanan, Balaraman; Praveen, Vakayil K.; John, Jubi

doi:10.1002/slct.202200548

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“…In just the last five years, there has been a remarkable development in silanol synthesis, especially the oxidative transformations from hydrosilanes (Scheme ). Among the recent additions to these oxidations are dehydrative couplings with water in the presence of metal catalysts or metal nanoparticles . Aerobic oxidation in the presence of transition metal catalysts has also been updated to use a cobalt or copper-NHPI catalyst .…”

Section: Introductionmentioning

confidence: 99%

Utilization of Silanols in Transition Metal-Catalyzed Organic Synthesis

2023

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The multifaceted implementation of silanols in organic synthesis is reviewed from the standpoint of developments in transition metal-catalyzed reactions. The major properties of silanols are summarized according to the research fields that have utilized these intriguing species: silanols as nucleophiles to serve as bulky surrogates for water; silanols as temporary ligands to control regioselectivity of metal-catalyzed reactions; silanols as coupling partners for transferring functional groups. These topics are summarized to provide opportunities for future developments in the chemistry of silanols.

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Section: Introductionmentioning

confidence: 99%