Understanding the optoelectronic profile and chemical stability of transition-metal dichalcogenides (TMDs) is crucial for advancing two-dimensional (2D) material applications, particularly in electronics, optoelectronics, and energy devices. Here, we investigate the structural, electronic, optical, and excitonic properties of the 1T′ WSe 2 monolayer. Phonon dispersion analysis confirmed the thermodynamic stability of this system. The 1T′ WSe 2 monolayer exhibits a small electronic band gap of 0.17 eV, and its linear optical response suggests the potential use as a polarizing filter due to its strong reflectivity at ŷlight polarization. Unlike the 1T′ MoS 2 system, 1T′ WSe 2 does not show an excitonic insulator phase. Instead, its exciton binding energy of 150 meV is consistent with values expected for 2D materials. This distinction underscores the unique electronic and optical properties of 1T′ WSe 2 , positioning it as a promising candidate for advanced technological applications such as flexible electronics, photodetectors, and quantum computing. By exploring these properties, we can unlock the full potential of TMDs in creating innovative highperformance devices.