An Armour Structure to Suppress the Brittle Failure of Ceramic Coatings

Abstract

The brittle failure of ceramic coatings limits their application in many fields. To address this issue, a novel armoured ceramic coating was developed to suppress brittle failure. First, an interconnected frame microstructure was micromachined onto the surface of a mild steel substrate using a nanosecond laser. Subsequently, a polymer-derived ceramic slurry was sprayed and sintered to obtain an armoured ceramic coating. The laser-micromachined burr-like microstructure of the substrate facilitated adhesion between the coating and the substrate. The results of the mechanical properties test showed that the armoured coating could withstand more than 20 cycles of water-cooled thermal shock at 600 °C, and the peeling area of the armoured coating was approximately three times less than that of the unarmoured coating under a normal load of 1471 N. The laboratory and field corrosion test results indicated that at high temperatures, the corrosion resistance of the armoured coating was comparable with that of the unarmoured coating and was approximately 10 times higher than that of the uncoated sample. The proposed method will aid in suppressing the brittle failure of ceramic coatings and broaden their scope of application in different fields.

Photochemically Inert Broad-Spectrum Sunscreen by Metal-Phenolic Network Coatings of Titanium Oxide Nanoparticles

“…12−14 However, the complete conformal ceramic coating is technically very challenging and mechanically fragile. 15,16 Synthetic polymers also have limitations as they can produce microplastic pollutants, plastic fragments under 5 mm diameter, which persist over extended periods due to their limited biodegradability. 17 Especially, microplastics can adsorb chemical pollutants in the marine environment and act as a reservoir of toxic compounds.…”

“…Coatings of TiO 2 nanoparticles (TiO 2 NPs) with ceramics or synthetic polymers have been widely studied to increase the dispersion stability and minimize the photocatalytic reaction. − However, the complete conformal ceramic coating is technically very challenging and mechanically fragile. , Synthetic polymers also have limitations as they can produce microplastic pollutants, plastic fragments under 5 mm diameter, which persist over extended periods due to their limited biodegradability . Especially, microplastics can adsorb chemical pollutants in the marine environment and act as a reservoir of toxic compounds. , Because of being toxic, persistent, and accumulative, microplastics became a particular concern for marine environmental health .…”