The convective and radiative heat transfer rates are calculated for the stagnation region of the Pioneer-Venus Probe vehicles during their entry flights into the planet Venus. The nonequilibrium thermochemical state of the flow is calculated using a viscous shock-layer method accounting for oxidation of the heat shield surface by atomic oxygen and for pyrolysis-gas injection. Radiative transport along the stagnation streamline is calculated using a line-by-line technique and tangent-slab approximation. For both radiative and convective heating rates, the present results are substantially smaller than the earlier values obtained assuming equilibrium. Nomenclature C = (pn)/(pjj) s D t = mass diffusion coefficient for species /, N-m-s/kg / = dimensionless velocity function, Eqs. (3) and (4) f w = normalized ablation rate, Eq. (21) f wp = normalized pyrolysis-gas injection rate, Eq. (19) g = normalized enthalpy g r = normalized energy gain by radiation J = number flux, mol/(m 2 -s) k = Boltzmann constant k w i = surface-oxidation velocity, m/s k w2 = surface-ionic recombination velocity for C + , m/s k w3 = surface-ionic recombination velocity for O + , m/s k w4 = sublimation velocity, m/s Mi = mass of species /, kg m = ablation rate, kg/(m 2 -s) m p = pyrolysis-gas injection rate, kg/(m 2 -s) Pr = Prandtl number p = pressure, Pa q c = convective heat transfer rate, W/m 2 q r = radiative heat transfer rate, W/m 2 q* = effective radiative heat transfer rate (q r + increment in q c because of radiation absorption), W/m 2 R = nose radius, m SCj = Schmidt number for species i T = temperature, K t = time, s u -velocity in x direction, m/s V f = freestream velocity, m/s v = velocity in y direction, m/s Wf = rate of production of species /, mol/(kg-s) x = distance along wall, m y = distance from wall, m /?! = surface-oxidation probability /3 2 = surface-ionic recombination probability for C + j8 3 = surface-ionic recombination probability for O + j8 4 = evaporation coefficient for C 3 ji = concentration of species i, mol/kg e = ionization fraction 77 = dimensionless distance in y direction, Eq. (2b) K = thermal conductivity, W/(m-K) JJL = viscosity, N-s/m 2 f = dimensionless distance in x direction, Eq. (2a) p = density, kg/m 3 Subscripts E = equilibrium / = freestream p = pyrolysis-gas s = immediately behind shock wave w = wall