“…The first paper regarding this topic was published in 2006, in which authors found a monotonic response of the emission intensity ratio of calcium lines with the surface strength of the concrete samples [12]. Since then, LIBS has been widely deemed as a promising hardness testing tool for various materials, such as tissues [13,14], steels and alloys [15][16][17][18][19][20], ceramics [21], and stones [22], via monitoring the variations of the parameters obtainable from plasma emission measurements, including spectral line intensity, excitation temperature, and electron density in plasma. Despite these excellent attempts to expand the scope of LIBS application, to the best of our knowledge, no experiments have been conducted aiming to investigate a possible approach for estimating grain size in RPG materials using LIBS.…”