2002
DOI: 10.1021/cm010751f
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An Antimony Sulfide with Copper Pillars:  [C4H12N2]0.5[CuSb6S10]

Abstract: A new copper-antimony sulfide, [C 4 H 12 N 2 ] 0.5 [CuSb 6 S 10 ], has been hydrothermally synthesized from binary metal sulfides in the presence of triethylenetetramine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, and SQUID magnetometry. The product (M r ) 1158.72) crystallizes in the monoclinic space group P2 1 /n with a ) 11.2578(4) Å, b ) 12.5259(5) Å, c ) 13.9390(7) Å, β ) 102.445(3)°, and V ) 1919.4 Å 3 . The structure consists of cyclic Sb 3 S 6 3units in … Show more

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Cited by 86 publications
(45 citation statements)
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“…Therefore, the integration of Cu(I) ions is beneficial to generate new multinary thioantimonates(III) with novel crystal structures and integrated physical properties. Representative examples of copper-containing thioantimonates(III) are [C 4 N 2 H 12 ] 0.5 [CuSb 6 S 10 ] [21], RCu 2 SbS 3 (R ¼ amine) [22,23] [25], and [Ni(dien) 2 ][CuSb 3 S 6 ] (dien ¼ diethylenetriamine) [25], in which organic cations or transition-metal complexes served as the templates. When the organic cations or transition-metal complexes were replaced by alkali or alkaline earth metal ions, six quaternary AeCueSbeS (A ¼ alkali or alkaline earth metals) thioantimonates(III) were obtained [26e29].…”
Section: Introductionmentioning
confidence: 99%
“…Therefore, the integration of Cu(I) ions is beneficial to generate new multinary thioantimonates(III) with novel crystal structures and integrated physical properties. Representative examples of copper-containing thioantimonates(III) are [C 4 N 2 H 12 ] 0.5 [CuSb 6 S 10 ] [21], RCu 2 SbS 3 (R ¼ amine) [22,23] [25], and [Ni(dien) 2 ][CuSb 3 S 6 ] (dien ¼ diethylenetriamine) [25], in which organic cations or transition-metal complexes served as the templates. When the organic cations or transition-metal complexes were replaced by alkali or alkaline earth metal ions, six quaternary AeCueSbeS (A ¼ alkali or alkaline earth metals) thioantimonates(III) were obtained [26e29].…”
Section: Introductionmentioning
confidence: 99%
“…[10][11][12][13][14][15][16] In contrast, transition metal M I (M = Cu, Ag) cations have diverse coordination modes (2,3,4) with chalcogen Q 2-(Q = S, Se) anions, and flexible linkages between M I Q x polyhedra. Generally, M I exists in the form of isolated M + or dimeric M 2 2+ to bridge main group thio-anionic building units, [17][18][19][20][21] or partially substitute the cation sites of supertetrahedral building units in low M I -containing 3D frame-1 ties. The icosahedral Cu 8 Se 13 clusters represent the first icosahedral Cu-Se unit found in 3D framework chalcogenides, and contain an unusual μ 8 -cubic bridging Se 2-ion at the core site.…”
Section: Introductionmentioning
confidence: 99%
“…In recent years, a large number of thioantimonates(III) with organic cations [1][2][3][4], transition metal complex cations [5][6][7][8][9][10][11][12][13][14][15][16][17][18] and other cations [19,20] serving as counterions to Sb x III S y nÀ anions, have been synthesized under hydro-or solvo-thermal conditions. The rich structural diversity of thioantimonates(III) results from variable coordination behaviors of Sb(III) atom caused by the stereochemically active lone pair [21].…”
Section: Introductionmentioning
confidence: 99%