“…In the method FUZR by Otto and Bandemer, a circle acts as the support of the fuzzy observations. Relative to the method FUZL by Massart et al, as support of the fuzzy observations, a line appeared to be more suitable.…”
Section: Resultsmentioning
confidence: 79%
“…It was compared with conventional ordinary and weighted least-squares and robust regression methods. The application of these different methods to relevant data sets proved that the performance of the procedure described in this paper exceeds that of the ordinary least-squares method and equals and often exceeds that of weighted or robust methods, including the two fuzzy methods proposed in refs and .…”
Section: Discussionmentioning
confidence: 86%
“…Because the weakness of the least-squares method lies in its overemphasis on large values of residuals, these should be deemphasized (downweighted) or perhaps even ignored. For intermediate values of the residuals, the procedure should connect the treatments of the small residuals and the extreme residuals in a smooth or fuzzy fashion. − …”
A new fuzzy regression algorithm is described and compared with conventional ordinary and weighted least-squares and robust regression methods. The application of these different methods to relevant data sets proves that the performance of the procedure described in this paper exceeds that of the ordinary least-squares method and equals and often exceeds that of weighted or robust methods, including the two fuzzy methods proposed previously (Otto, M.; Bandemer, H., Chemom. Intell. Lab. Syst. 1986, 1, 71. Hu, Y.; Smeyers-Verbeke, J.; Massart, D. L. Chemom. Intell. Lab. Syst. 1990, 8, 143). Moreover, we emphasize the effectiveness and the generality of the two new criteria proposed in this paper for diagnosing the linearity of calibration lines in analytical chemistry.
“…In the method FUZR by Otto and Bandemer, a circle acts as the support of the fuzzy observations. Relative to the method FUZL by Massart et al, as support of the fuzzy observations, a line appeared to be more suitable.…”
Section: Resultsmentioning
confidence: 79%
“…It was compared with conventional ordinary and weighted least-squares and robust regression methods. The application of these different methods to relevant data sets proved that the performance of the procedure described in this paper exceeds that of the ordinary least-squares method and equals and often exceeds that of weighted or robust methods, including the two fuzzy methods proposed in refs and .…”
Section: Discussionmentioning
confidence: 86%
“…Because the weakness of the least-squares method lies in its overemphasis on large values of residuals, these should be deemphasized (downweighted) or perhaps even ignored. For intermediate values of the residuals, the procedure should connect the treatments of the small residuals and the extreme residuals in a smooth or fuzzy fashion. − …”
A new fuzzy regression algorithm is described and compared with conventional ordinary and weighted least-squares and robust regression methods. The application of these different methods to relevant data sets proves that the performance of the procedure described in this paper exceeds that of the ordinary least-squares method and equals and often exceeds that of weighted or robust methods, including the two fuzzy methods proposed previously (Otto, M.; Bandemer, H., Chemom. Intell. Lab. Syst. 1986, 1, 71. Hu, Y.; Smeyers-Verbeke, J.; Massart, D. L. Chemom. Intell. Lab. Syst. 1990, 8, 143). Moreover, we emphasize the effectiveness and the generality of the two new criteria proposed in this paper for diagnosing the linearity of calibration lines in analytical chemistry.
“…** The stop criterion was fulfilled when more than half of the measurements had a membership value of 0.1 (= H) or more. 3 We carried out fuzzy linear calibration for three selected data sets investigated by them: those for data sets 2, 5 and 8. These were of interest because they were measured with gross outlier, no outliers and with model error, respectively.…”
Section: Model Error Caused By Difference From the Assumed Linearity mentioning
In every mathematical (e.g., statistical) procedure and theorem used in calibration, several conditions need to be fulfilled. What can analysts and chemometricians do, however, if the conditions are only nearly fulfilled? One can expect that small changes in the conditions yield only small changes in the results. This article shows how to treat two types of model error caused by assuming an incorrect error distribution or relationship (i.e., linear). The procedures applied are based on robust statistics and fuzzy theory, respectively.
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