Abstract:An approach which considers both nuclear and electronic motions for molecular systems is derived using algebraic techniques within the vector model. The dynamical symmetries of the Hamiltonian thus derived are examined and shown to account for the analytic diagonalizability of the LEPS level potential function for molecular systems. The initial application is to the H, collision system, demonstrating the ability of the model to treat systems without bound states. Extensions to more complicated systems are also… Show more
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