Ball-on-disc tribo tests and atomic force microscopy (AFM) were used to analyze the effect of base oil polarity on the friction behaviour of steel-steel contacts lubricated with base oil + zinc dialkyldithiophosphate (ZDDP) solutions. Understanding the lubrication properties of the first chemisorbed layer of additives on work pieces yields important information for the optimization of lubrication in various solutions, in particular with regard to the type of additive and amount needed.To characterize the influence of oil polarity, two reference base oils (hexadecane -non polar and diethylenglycol -polar) were blended with different concentrations of ZDDP-C 4 , and the solutions were tested. A monolayer of base oil/additive solution is deposited on an ASI 52100 steel plate and is scanned on AFM contact mode under several rubbing time and applied load conditions. An AFM technique is developed to estimate microscopic values of friction coefficients showing how the oil polarity contributes to the differences in friction behaviour of the solution due to the addition of ZDDP.