“…One dimensional (1D) semiconductor nanowires (NWs) based on ZnO have been successfully assembled into various kinds of short-wave optoelectronic (OE) devices for wide potential applications and green synthetic processing over years because they exhibit strong excitonic effects due to their direct wide band gap of 3.3 eV at room temperature and their large exciton binding energy of 60 meV. − However, the difficulties inherent in the fabrication of high quality p-type ZnO nanowires have hindered their application in light-emitting devices (LEDs) and photovoltaic (PV) devices based on ZnO homojunctions. − As an alternative approach, ZnO/GaN heterojunction devices, particularly in LEDs, have been achieved and are continuously being improved with elaborate designs by virtue of the similarity in physical properties especially the small lattice mismatch (1.8%) between ZnO and GaN. − Interestingly, with the development of nanotechnology more and more research groups pay much attention to fabricating OE devices based on a single nanowire (SNW) in recent years because SNW OE device is more favorable than others attributed to the requirement for the integration down to nanoscale and better controllability over parameters compared to the average information of nonuniform samples. ,, Additionally, these nanowire-based functional elements, such as nanolasers, , photodetectors, field effect transistors, , and a host of other devices, have attracted a great deal of attention and have been demonstrated. Nevertheless, the study of nanodevices of LEDs based on single heterostuctured NW has rarely been reported, although there have been many efforts directed toward the heterojunction synthesis containing SNW and thin film. ,, …”