“…Ascorbate oxidase was largely used for the development of biosensors devoted to AA detection in different matrices: in red and white wines (Campanella et al, 2004;Vig et al, 2010), in commercial fruit juices (Wang et al, 2008), in natural fruit juices and soft drinks (Pisoschi et al, 2010), in fruit juices and vitamin C tablets (Chauhan et al, 2010).…”
“…Ascorbate oxidase was largely used for the development of biosensors devoted to AA detection in different matrices: in red and white wines (Campanella et al, 2004;Vig et al, 2010), in commercial fruit juices (Wang et al, 2008), in natural fruit juices and soft drinks (Pisoschi et al, 2010), in fruit juices and vitamin C tablets (Chauhan et al, 2010).…”
“…And the larger peak current value could be observed from IAA. The possible mechanism of this electrochemical phenomenon was raised as follows: After the AO/dpAu/rGO/GCE was immersed in AA or IAA solution, the AA around the electrode could be chemically catalyzed by AO to generate DHA (Scheme 1C), 36,37 which led to a lower amount of AA reaching the electrode surface, 20 so that a lower oxidation peak current was observed on AA. Compared with the dpAu/rGO/GCE, the increased peak current of IAA was observed on the AO/dpAu/ rGO/GCE, hinted that the compatible microenvironment on the selective biointerface was more appropriate to IAA via specific electrostatic or hydrogen bonding sites, 38 so that a greater amount of IAA loading was acquired on the AO/dpAu/rGO/ GCE, derived from the synergistic effect of rGO, dpAu and AO.…”
Section: Stereoselective Interaction Of Aa and Iaamentioning
“…Common strategies include acid-base and redox titrations, fluorometry, photometry and spectroscopy [11][12][13][14][15][16][17][18]. Electrochemical determination of AA is facilitated by the ease of anodic oxidation of the molecule to dehydroascorbic acid (DHAA).…”
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