Aminoethylglycine-Functionalized Ru(bpy)₃²⁺ with Pendant Bipyridines Self-Assemble Multimetallic Complexes by Copper and Zinc Coordination

Abstract

In this paper, we presented emission lifetime data for a series of aminoethylglycine-functionalized Ru(bpy) 3 2þ compounds with coordinated copper or zinc. However, we found that the calculations of the radiative and nonradiative relaxation rates (k r and k nr , respectively) were incorrect because the wrong equation was used. The correct values and equations are given in the corrected Table 2. Note that these corrected values do not change the interpretation of the results.

Synthetic, ′inorganic DNA′ as a means to high-density molecular electronics

“…Using a specific solvent system (5 ACN:2 H 2 O:1 KNO 3 ) in a high performance liquid chromatography (HPLC) system, we are able to separate these compounds based on charge in a reverse-phase silica column. Figure 6: Formation of several isomers from basic iDNA building blocks [3] This process is able to separate most of the isomers that are created, since they will have varying amounts of charged metal atoms in them. Analysis of the separation of the products of a synthesis can possibly assist in the creation of a more controlled synthesis of the desired isomer (in most cases, the antiparallel, controlled length chain).…”