Amine functional magnetic nanoparticles via waterborne thiol–ene suspension photopolymerization for antibody immobilization

Isosorbide Diallyl Based Antibacterial Thiol–Ene Photocured Coatings Containing Polymerizable Fluorous Quaternary Phosphonium Salt

“…All these FTIR findings are in good agreement with the literature. 51,52 After curing, the thiol and the allyl bands completely disappeared (Figure S6B). Additionally, as the concentration of the PFQPS was increased in the formulation, a band at around 1590 cm −1 was observed in the FTIR spectra of the formulations and this band was attributed to the aromatic −CC− double bond vibrations.…”

Droplet nucleation in miniemulsion thiol–ene step photopolymerization

“…13,14 The main examples result from a miniemulsion photopolymerization, [15][16][17][18][19][20][21][22][23][24] and to a less extent, dispersion 25,26 and emulsion 12,27 (photo)polymerizations. Suspension photopolymerization has been also described, [28][29][30][31][32] but this process does not result in polymer colloids (average particle diameter < 1 µm), but in micrometre solid beads (0.1 -10 mm). Although copolymers of acrylic and methacrylic acids and esters account for a major fraction of all industrial latexes, they have significant drawbacks.…”

Acetylene Dicarboxylic Acid Diallyl Ester: A Versatile Monomer for Thiol–Ene Photocured Networks

“…[3][4][5][6][7] Almost all types of -ene molecules such as allyls, vinylic compounds, acrylates, methacrylates, and maleimides, undergo TEP reactions with thiols via radical induced step-growth mechanism. [8][9][10] TEP can be used to prepare antibacterial coatings, [11] biobased photocured coatings, [12][13][14] adsorbent materials, [15] 3D printed objects, [16] biomolecule immobilization, [17][18][19][20][21] preparation of DOI: 10.1002/mame.202100427 microfluidic devices, [22] hydrophobic coatings, [23][24] and so on. In the case of photocurable coatings, TEP emerges as a very revolutionary method as it produces nontacky surfaces within seconds due its resistance to oxygen inhibition.…”