Amine-Borane-Mediated, Nickel/Photoredox-Catalyzed Cross-Electrophile Coupling between Alkyl and Aryl Bromides
Ke-Rong Li,
Xian-Chen He,
Jie Gao
et al.
Abstract:Nickel/photoredox catalysis has emerged as a powerful platform for exploring nontraditional and challenging crosscouplings. Herein, a metallaphotoredox catalytic protocol has been developed on the basis of a tertiary amine-ligated boryl radicalinduced halogen atom transfer process under blue-light irradiation. A wide variety of aryl and heteroaryl bromides featuring different functional groups and pharmaceutical moieties were facilely coupled to rapidly install C(sp 3 )-enriched aromatic scaffolds. The compati… Show more
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