“…N-Halo amines have long been used as reagents for amination of aromatic compounds (see [105][106][107][108][109] and references therein). The amination of benzene, toluene, tert-butylbenzene, N,N-dimethylaniline, and naphthalene with chloro(dimethyl)amine in nitromethane or nitropropane in the presence of AlCl 3 gave the corresponding dimethylamino-substituted arenes in 90, 54, 47, 21, and 32% yield, respectively [105].…”