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Yakhvarov, Dmitry G.; Budnikova, Yu. G.; Tazeev, D. I.; Sinyashin, Оleg G.

doi:10.1023/a:1021611926712

Cited by 17 publications

(5 citation statements)

References 9 publications

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“…For example, zinc metal is sometimes employed as a sink so that phosphorous will bind with zinc rather than with the active metal, allowing for the reactivity of the active metal to be retained. [38][39][40] In an attempt to prevent phosphorous compounds from binding nickel, zinc was therefore added to the catalyst (12% Ni/3% Zn/Al 2 O 3 ). Unfortunately, zinc did not prohibit the binding of phosphorous to nickel and led to a similar outcome (shown in Fig.…”

Section: Resultsmentioning

confidence: 99%

Phosphate assisted integrated carbon dioxide capture and conversion to methane

Koch

Alagaratnam

Goeppert

et al. 2023

Sustainable Energy Fuels

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Section: Resultsmentioning

confidence: 99%

Phosphate assisted integrated carbon dioxide capture and conversion to methane

Koch

Alagaratnam

Goeppert

et al. 2023

Sustainable Energy Fuels

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“…However, there are some examples for such reactions. In 2002, Budnikova et al investigated the electrochemical arylation of white phosphorus with aryl halides in the presence of Ni(BF 4 ) 2 bpy 2 . Depending on the anode material and the aryl halide, different products are favored.…”

Section: Arylation Of Specific Groupsmentioning

confidence: 99%

Electrochemical Arylation Reaction

et al. 2018

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Arylated products are found in various fields of chemistry and represent essential entities for many applications. Therefore, the formation of this structural feature represents a central issue of contemporary organic synthesis. By the action of electricity the necessity of leaving groups, metal catalysts, stoichiometric oxidizers, or reducing agents can be omitted in part or even completely. The replacement of conventional reagents by sustainable electricity not only will be environmentally benign but also allows significant short cuts in electrochemical synthesis. In addition, this methodology can be considered as inherently safe. The current survey is organized in cathodic and anodic conversions as well as by the number of leaving groups being involved. In some electroconversions the reagents used are regenerated at the electrode, whereas in other electrotransformations free radical sequences are exploited to afford a highly sustainable process. The electrochemical formation of the aryl-substrate bond is discussed for aromatic substrates, heterocycles, other multiple bond systems, and even at saturated carbon substrates. This survey covers most of the seminal work and the advances of the past two decades in this area.

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“…Note that the metal ions generated from the electrochemically soluble (sacrificial) anode are required to stabilize anionic phosphido intermediates and thus prevent undesired phosphorus polymerization processes. Depending on the anode material, different organophosphorus products are formed [84] . While a zinc anode mainly leads to the formation of tertiary phosphanes, an aluminium anode instead results in phosphane oxide formation.…”

Section: Transition‐metal‐mediated Functionalization Of White Phosphorusmentioning

confidence: 99%

“…Depending on the anode material, different organophosphorus products are formed. [84] While az inc anode mainly leads to the formation of tertiaryp hosphanes, an aluminium anode insteadr esults in phosphane oxide formation. By contrast, use of am agnesium anode gives cyclic polyphosphorus compounds, such as (PhP) 5 .…”

Section: Radical Functionalization Of Pmentioning

confidence: 99%

Transition‐Metal‐Mediated Functionalization of White Phosphorus

Hoidn

Scott

Wolf

2020

Chemistry A European J

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Recently there has been great interest in the reactivity of transition‐metal (TM) centers towards white phosphorus (P4). This has ultimately been motivated by a desire to find TM‐mediated alternatives to the current industrial routes used to transform P4 into myriad useful P‐containing products, which are typically indirect, wasteful, and highly hazardous. Such a TM‐mediated process can be divided into two steps: activation of P4 to generate a polyphosphorus complex TM‐Pn, and subsequent functionalization of this complex to release the desired phosphorus‐containing product. The former step has by now become well established, allowing the isolation of many different TM‐Pn products. In contrast, productive functionalization of these complexes has proven extremely challenging and has been achieved only in a relative handful of cases. In this review we provide a comprehensive summary of successful TM‐Pn functionalization reactions, where TM‐Pn must be accessible by reaction of a TM precursor with P4. We hope that this will provide a useful resource for continuing efforts that are working towards this highly challenging goal of modern synthetic chemistry.

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Untitled

Cited by 17 publications

References 9 publications

Phosphate assisted integrated carbon dioxide capture and conversion to methane

Phosphate assisted integrated carbon dioxide capture and conversion to methane

Electrochemical Arylation Reaction

Transition‐Metal‐Mediated Functionalization of White Phosphorus

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