Alternative methods for production of alicyclic epoxides

Vereshchagina, N. V.; Antonova, T. N.; Абрамов, И. Г.; Kopushkina, G. Yu.

doi:10.1134/s0965544114030116

Pet. Chem.

2014

DOI: 10.1134/s0965544114030116

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Alternative methods for production of alicyclic epoxides

N. V. Vereshchagina

T. N. Antonova

И. Г. Абрамов

et al.

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Cited by 6 publications

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“…Furthermore, oxygen containing dicyclo pentene derivatives are of interest for the fabrication of polymers, liquid crystals, and other materials [1][2][3][4].…”

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confidence: 99%

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Features of dicyclopentene formation during hydrogenation of dicyclopentadiene

et al. 2016

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Abstracts-General trends and specific features of the reaction of dicyclopentadiene (tricyclo[5.2.1.0 2.6 ]dec adiene 3,8) hydrogenation to dicyclopentene (tricycle[5.2.1.0 2.6 ]decene 3) with hydrogen in the liquid phase under mild conditions at atmospheric pressure over a finely divided 1% Pd/C catalyst have been studied. The kinetic parameters that characterize the effect of the solvent nature, catalyst concentration, and temperature on the rate of hydrogen uptake in the hydrogenation process have been determined. To substantiate the con clusion of the sequence of saturation of the dicyclopentadiene double bonds in terms of the mechanism of heterogeneous catalysis, their reactivity has been compared. It has been shown that in the presence of a num ber of functionalized aromatic compounds as a stabilizing additive, the yield of desired dicyclopentene increases to 98.5-99 mol % with the complete conversion of dicyclopentadiene. The structure of dicyclopen tadiene and its hydrogenation product dicyclopentene has been confirmed using spectroscopic methods.

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“…Furthermore, oxygen containing dicyclo pentene derivatives are of interest for the fabrication of polymers, liquid crystals, and other materials [1][2][3][4].…”

mentioning

confidence: 99%

“…Solvent: toluene; C 0 DCPD = 0.8 mol/dm 3 ; C cat = Rate curves for (a) substrate consumption in the hydrogenation of (1, 2) dicyclopentadiene to dicyclopentene and(3,4) dicyclopentene to dicyclopentane and (2', 3') dicyclopentene and dicyclopentane buildup rate curves, respectively. (b) Tempera ture dependence of the rate of the process.…”

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confidence: 99%

Features of dicyclopentene formation during hydrogenation of dicyclopentadiene

et al. 2016

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Liquid-phase heterogeneous hydrogenation of dicyclopentadiene

et al. 2022

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Saturation kinetics and relative reactivity of the double bonds of alicyclic dienes in their hydrogenation

et al. 2017

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Alternative methods for production of alicyclic epoxides

Cited by 6 publications

References 2 publications

Features of dicyclopentene formation during hydrogenation of dicyclopentadiene

Features of dicyclopentene formation during hydrogenation of dicyclopentadiene

Liquid-phase heterogeneous hydrogenation of dicyclopentadiene

Saturation kinetics and relative reactivity of the double bonds of alicyclic dienes in their hydrogenation

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