Alternating Copolymerization in the Presence of Lewis Acids

Bamford, C. H.

doi:10.1007/978-1-4757-9139-6_3

Cited by 14 publications

(1 citation statement)

References 87 publications

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“…This results in higher k p values. Lewis acids of metal salts demonstrate similar behavior forming co‐ordinate bonds with the carbonyl groups in polar monomers 12–14. Bamford et al14 were the first to demonstrate that the presence of a Li ion during polymerization of acrylonitrile resulted in increased rate of polymerization and consequently higher molecular weight polymers.…”

Section: Effect Of Interacting Species On Frpmentioning

confidence: 99%

Living Radical Polymerization and Molecular Imprinting: Improving Polymer Morphology in Imprinted Polymers

Salian

Byrne

2012

Macro Materials & Eng

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Living radical polymerization (LRP) techniques and their ability to improve the morphology of crosslinked polymer networks by controlling polymer chain growth are reviewed. Recent successes in the creation of improved molecularly imprinted polymer networks are also discussed. LRP offers the ability to control molecular weight, polydispersity, and tacticity while reducing microgel formation in polymers created via free-radical polymerization (FRP). The improved network architecture of polymers created via LRP has great potential, especially when considering imprinted networks which have traditionally been plagued by heterogeneity in network morphology and binding affinities. Using LRP can considerably improve template recognition and further delay template transport in imprinted polymers.

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Section: Effect Of Interacting Species On Frpmentioning

confidence: 99%

Living Radical Polymerization and Molecular Imprinting: Improving Polymer Morphology in Imprinted Polymers

Salian

Byrne

2012

Macro Materials & Eng

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Radical polymerization of methyl methacrylate in the presence of magnesium bromide as the Lewis acid

Matsumoto

Nakamura

1999

J. Appl. Polym. Sci.

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ABSTRACT:We carried out the radical polymerization of methyl methacrylate (MMA) at 0 -80°C in the presence of magnesium bromide. The polymerization rate and the molecular weight of the resulting polymers increased according to the amount of the added magnesium bromide as the Lewis acid. It was revealed that the microtacticity of the polymer depended on the amount of magnesium bromide. The effects of the solid surface of magnesium bromide, which is partly soluble in the polymerization systems, were also investigated. The results obtained in this work were compared with the results reported for the polymerization systems in the presence of the other Lewis acids.

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Sequence‐Controlled Polymers by Chain Polymerization

Ren

Mastan

2017

Sequence‐Controlled Polymers

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Alternating Copolymerization in the Presence of Lewis Acids

Cited by 14 publications

References 87 publications

Living Radical Polymerization and Molecular Imprinting: Improving Polymer Morphology in Imprinted Polymers

Living Radical Polymerization and Molecular Imprinting: Improving Polymer Morphology in Imprinted Polymers

Radical polymerization of methyl methacrylate in the presence of magnesium bromide as the Lewis acid

Sequence‐Controlled Polymers by Chain Polymerization

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