Alternating copolymer graft copolymers. IV. Grafting of alternating copolymers onto precomplexed polymers

Gaylord, Norman G.; Patnaik, Birendra K.; Štolka, M.

doi:10.1002/pol.1971.110091210

Cited by 7 publications

(2 citation statements)

References 3 publications

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“…Figure3. FT-IR spectrum of (a) virgin poly (CAN/CHD),(b) the KF/TBABr elimination product of poly (CAN/CHD), (c) the thermal elimination product of poly (CAN/CHD), and (d) the KF/TBABr elimination product of brominated poly (CAN / CHD).…”

mentioning

confidence: 99%

Structural analysis of the alternating copolymer poly(chloroacrylonitrile-alt-cyclohexadiene)

Panchalingam¹,

Reynolds²

1988

Macromolecules

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mentioning

confidence: 99%

Structural analysis of the alternating copolymer poly(chloroacrylonitrile-alt-cyclohexadiene)

Panchalingam¹,

Reynolds²

1988

Macromolecules

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“…Copolymerizations initiated by UV radiation, electrical current and radical initiators, have been described as cis ‐1.4 addition with charge transfer complex (CTC) participation 12. 13 Some of the other conjugated dienes which also copolymerize in 1:1 fashion with MA include 2,3‐dimethylbutadiene,14–16 2,3‐dichlorobutadiene, 1‐cyclohexyloxy‐1,3‐butadiene,17 2,3‐bis(diethylphosphonono)‐1,3‐butadiene,18 2,4‐hexadiene,19 1,3‐pentadienes,20, 21 1,1‐dichloropropyl‐1,3‐butadiene,22 1‐methoxy‐1,3‐butadiene,23 and cis ‐ and trans ‐1,3‐pentadiene 24…”

Section: Functional Macromonomers and Hyperbranched Macromolecular Armentioning

confidence: 99%

Hyperbranched macromolecules through donor‐acceptor type copolymerization of allyl–vinylene bifunctional monomers

Rzaev

2002

Polymer International

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Present review is an attempt to generalize and systematize the results accumulated in synthesis of cyclolinear and hyperbranched reactive macromolecules via radical alternating copolymerization of various bifunctional monomers containing donor and acceptor type double bonds. Synthesis of hyperbranched reactive macromolecules was carried out using complex‐radical cyclocopolymerization of donor‐acceptor type bifunctional monomers such as monoallyl ester of maleic acid (MAM), allyl acrylate (AA), allyl methacrylate (AM), allyl trans‐cinnamate (AC), methylallylmaleate (MeAM), methylallylfumarate (MAF) and allyl‐α‐(N‐maleimido)acetate (AMI), and maleic anhydride (MA) and styrene (St) as typical acceptor and donor comonomers, respectively. The kinetic parameters of these reactions, constants of cyclization, complex‐formation and copolymerization, as well as the ratios of chain growth rates for the participation of monomeric charge transfer complexes and free monomers, were all determined. It was demonstrated that in the studied systems, copolymerizations predominantly proceed according to alternating mechanism with formation of macromolecules having cyclolinear structure in the steady‐state and hyperbranched structure in the high conversion conditions. It was shown that formation of linear and hyperbranched macromolecules containing allyl or vinylene groups in the side chain occurs selectively carry out and depends on the nature of used comonomer. General schemes and proposed mechanism of hyperbranching and crosslinking reactions were also described. Some useful properties of synthesized reactive copolymers were discussed. © 2002 Society of Chemical Industry.

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Mechanism of alternating copolymerization—I. Kinetic method for the determination of the ratio of constants for the addition of donor-acceptor complexes and free monomers to the propagating centre

Georgiev

Zubov

1978

European Polymer Journal

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Alternating copolymer graft copolymers. IV. Grafting of alternating copolymers onto precomplexed polymers

Cited by 7 publications

References 3 publications

Structural analysis of the alternating copolymer poly(chloroacrylonitrile-alt-cyclohexadiene)

Structural analysis of the alternating copolymer poly(chloroacrylonitrile-alt-cyclohexadiene)

Hyperbranched macromolecules through donor‐acceptor type copolymerization of allyl–vinylene bifunctional monomers

Mechanism of alternating copolymerization—I. Kinetic method for the determination of the ratio of constants for the addition of donor-acceptor complexes and free monomers to the propagating centre

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