The β + /EC decay of 180 Tl and excited states in the daughter nucleus 180 Hg have been investigated at the CERN On-Line Isotope Mass Separator (ISOLDE) facility. Many new low-lying energy levels were observed in 180 Hg, of which the most significant are the 0 + 2 at 419.6 keV and the 2 + 2 at 601.3 keV. The former is the bandhead of an excited band in 180 Hg assumed originally to be of prolate nature. From the β feeding to the different states in 180 Hg, the ground-state spin of 180 Tl was deduced to be (4 − ,5 − ).