An in-house designed
membrane process suitable for subsea natural
gas dehydration was studied. The use of a membrane absorber together
with a thermopervaporation (TPV) unit for solvent regeneration in
a closed loop enables the effective and clean production of high-pressure
natural gas close to the wellhead. This process avoids the continuous
chemical injection for preventing hydrate formation in natural gas
pipelines. The regeneration of the absorbent agent (triethylene glycol
(TEG)) by TPV in the closed loop is highly energy-efficient, owing
to the unlimited free cooling energy from the cold subsea water. In
this work, the performance of membranes in TPV for TEG regeneration
was evaluated experimentally for the first time. Morphological and
permeation characterizations of an AF2400 thin-film composite membrane
were carried out, and high separation factors outperforming the vapor–liquid
equilibrium (VLE) were obtained for the solutions containing various
water contents at feed temperatures ranging from 30 to 70 °C.
The highest values of a separation factor (128,000) and a permeability
(2380 (Barrer)) were obtained for the TEG solution containing 30 wt
% water at 30 °C, while the highest water flux (468 (g/m2·h)) was reached at 70 °C. Moreover, the concentration
polarization phenomenon induced by the temperature gradient was revealed
in the membrane’s vicinity of the feed channel. A 3D computational
fluid dynamics simulation was performed over the entire module to
correct the driving force for a more precise assessment of the membrane
permeance. The temperature and concentration profiles in the membrane
module domains were explored, and a good agreement with experimental
data was obtained.