All-solid secondary polyaniline-zinc battery

Sivaraman, P.; Thakur, Avinash P.; Kushwaha, Rajesh; Ratna, Debdatta; Samui, A. B.

doi:10.1007/s10800-007-9422-1

Cited by 18 publications

(4 citation statements)

References 27 publications

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“…Those reasons result in an immense barrier that prevents industrialization and extensive application of Zn//PANI batteries. [17][18][19][20][21] Various attempts have been made to overcome above limitations, and including the improving aniline polymerization conditions for high cell discharge capacity, changing the cell charge style to prohibit degradation, adding other metals to modify zinc electrode, supplying appropriate additives to the electrolyte for decreasing the charge/discharge time, inhibiting zinc dendrite formation, and preventing the electrode corrosion. [22][23][24][25][26][27][28][29] Some effective improvement measures have been proposed.…”

mentioning

confidence: 99%

Acetate as Electrolyte for High Performance Rechargeable Zn-Mn-Deposited Zn/Ni Foam-Supported Polyaniline Composite Battery

Cao

et al. 2019

J. Electrochem. Soc.

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Increased electroactivity of polyaniline prior doped with lithium ions is observed during polymerization by cyclic voltammograms (CV) compared with pure polyaniline. The electrochemical performance of a three-dimensional nickel foam-supported polyaniline composite prepared by electrophoresis and a casting process was investigated at different low-vacuum pressures for casting the aforementioned slurry. An appropriate vacuum pressure of 3000 Pa was certified by cyclic voltammetry and scanning electron microscopy. The nickel foam-supported polyaniline composite cathode were prepared and observed with prohibited hydrogen evolution and the enhanced conductivity in a manganese acetate-zinc acetate solution electrolyte system with lithium ions additive. The deposited zinc anode prepared by co-electrodeposition of zinc-manganese exhibited with high discharge voltage and stable discharge platform. The zinc-manganese-deposited zinc//nickel foam-supported polyaniline composite battery exhibited significant improvement in the capacity density and cycle performance. A discharge capacity density of 142.3 mAh.g −1 was attained by the battery, and it was maintained more than 94.7% of the original value after 60 cycles, and there was no distinct change in the coulomb efficiency with an average value of 90% over the experiment, which indicates that the present cell has promising possibility for use as an energy storage or high-performance rechargeable battery.

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confidence: 99%

Acetate as Electrolyte for High Performance Rechargeable Zn-Mn-Deposited Zn/Ni Foam-Supported Polyaniline Composite Battery

Cao

et al. 2019

J. Electrochem. Soc.

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“…Then, at the interface between polymer and fillers, ionic conduction can be improved. Sivaraman et al [164] developed a PEO/ZnSO 4 /nanoclay-based gel polymer electrolyte for a Zn-PANI battery. The ionic conductivity of 5.54 × 10 −4 S cm −1 is obtained with a weight ratio of PEO/ZnSO 4 /nanoclay of 10/5/0.75.…”

Section: Wwwadvancedsciencenewscommentioning

confidence: 99%

Recent Advances in Polymer Electrolytes for Zinc Ion Batteries: Mechanisms, Properties, and Perspectives

Huang

et al. 2020

Advanced Energy Materials

361

240

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Aqueous rechargeable zinc ion batteries (ZIBs) have been deemed to be possible candidates for large‐scale energy storage due to their ecoefficiency, substantial reserve, safety, and low cost. However, the challenges inherent in aqueous electrolytes, such as water splitting reactions, water evaporation, and liquid leakage, have greatly hindered their development in energy storage. Fortunately, polymer electrolytes would be able to overcome the abovementioned challenges. Moreover, the flexible properties of polymer electrolytes can facilitate their future application in wearable electronics. Recently, increasing attention has been attracted to the polymer electrolyte‐based zinc ion batteries. However, the development of polymer electrolytes for ZIBs is still in the early stages due to numerous challenges. Therefore, substantial research effort is required to overcome the challenges of polymer electrolyte‐based ZIBs. In this review, the current progress in developing polymer electrolytes, including solid polymer electrolytes, gel polymer electrolytes, and hybrid polymer electrolytes, as well as the interactions between electrodes and polymer electrolytes for ZIBs is comprehensively reviewed, analyzed, and discussed in terms of their synthesis, characterization, and performance validation. To facilitate further research and development of polymer electrolytes for ZIBs, the relevant challenges are summarized and analyzed, and some underlying approaches to overcome these challenges are also proposed.

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“…Sivaraman et al [129] added organically modified clay to build a PEO/ZnSO 4 /nanoclay electrolyte. The resulting material exhibited the highest ionic conductivity when the weight ratio of PEO/ZnSO 4 /nanoclay was 10/5/0.75, reaching a value of 5.54 × 10 −4 S cm −1 .…”

Section: Other Electrolytesmentioning

confidence: 99%

A Minireview of the Solid-State Electrolytes for Zinc Batteries

Yao,

Zheng,

Zhou

et al. 2023

Polymers

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Aqueous zinc-ion batteries (ZIBs) have gained significant recognition as highly promising rechargeable batteries for the future due to their exceptional safety, low operating costs, and environmental advantages. Nevertheless, the widespread utilization of ZIBs for energy storage has been hindered by inherent challenges associated with aqueous electrolytes, including water decomposition reactions, evaporation, and liquid leakage. Fortunately, recent advances in solid-state electrolyte research have demonstrated great potential in resolving these challenges. Moreover, the flexibility and new chemistry of solid-state electrolytes offer further opportunities for their applications in wearable electronic devices and multifunctional settings. Nonetheless, despite the growing popularity of solid-state electrolyte-based-ZIBs in recent years, the development of solid-state electrolytes is still in its early stages. Bridging the substantial gap that exists is crucial before solid-state ZIBs become a practical reality. This review presents the advancements in various types of solid-state electrolytes for ZIBs, including film separators, inorganic additives, and organic polymers. Furthermore, it discusses the performance and impact of solid-state electrolytes. Finally, it outlines future directions for the development of solid-state ZIBs.

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All-solid secondary polyaniline-zinc battery

Cited by 18 publications

References 27 publications

Acetate as Electrolyte for High Performance Rechargeable Zn-Mn-Deposited Zn/Ni Foam-Supported Polyaniline Composite Battery

Acetate as Electrolyte for High Performance Rechargeable Zn-Mn-Deposited Zn/Ni Foam-Supported Polyaniline Composite Battery

Recent Advances in Polymer Electrolytes for Zinc Ion Batteries: Mechanisms, Properties, and Perspectives

A Minireview of the Solid-State Electrolytes for Zinc Batteries

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