Let G and H be finite graphs without loops or multiple edges. If for any two-coloring of the edges of a complete graph K n , there is a copy of G in the first color, red, or a copy of H in the second color, blue, we will say K n → (G, H). The Ramsey number r(G, H) is defined as the smallest positive integer n such thatis called a critical coloring. A Ramsey critical r(G, H) graph is a graph induced by the first color of a critical coloring. In this paper, when n ≥ 15, we show that there exist exactly sixty eight non-isomorphic Ramsey critical r(C n , K 6 ) graphs.