All-carbon positive electrodes for stable aluminium batteries

Zhou, Zhili; Li, Na; Wang, Peng; Song, Wei‐Li; Jiao, Shuqiang; Chen, Haosen; Fang, Daining

doi:10.1016/j.jechem.2019.03.027

Cited by 31 publications

(24 citation statements)

References 43 publications

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“…124 Current collectors can be also made from carbonaceous and polymeric materials with various dimensions. 125 Typical building blocks includes CNTs, [126][127][128] carbon fibers, [129][130][131][132][133] carbon cloth (CC), 134,135 graphene, [136][137][138][139] polyacrylonitrile (PAN), 140,141 cellulose, [142][143][144] and their hybrids. 145 These current collectors are featured with high flexibility, extraordinary conductivity, light weight and large surface area, favoring mass/charge transport, active material supports, and volume change accommodation.…”

Section: Flexible Current Collectorsmentioning

confidence: 99%

Advanced energy materials for flexible batteries in energy storage: A review

et al. 2020

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Smart energy storage has revolutionized portable electronics and electrical vehicles. The current smart energy storage devices have penetrated into flexible electronic markets at an unprecedented rate. Flexible batteries are key power sources to enable vast flexible devices, which put forward additional requirements, such as bendable, twistable, stretchable, and ultrathin, to adapt mechanical deformation under the working conditions. This review summarizes the recent advances in construction and configuration of flexible batteries and discusses the general metrics to benchmark various flexible batteries with different materials and chemistries. Moreover, we present advanced prototype flexible batteries developed by some companies to afford general envision of the technological status. Lastly, the critical points are summarized in the development of flexible batteries and remaining challenges are also presented for the future design of flexible batteries in practical perspectives. K E Y W O R D S composite electrode, flexible batteries, smart energy storage, ultrathin batteries, wearable electronics 1 | INTRODUCTION Rechargeable batteries have popularized in smart electrical energy storage in view of energy density, power density, cyclability, and technical maturity. 1-5 A great success has been witnessed in the application of lithium-ion (Li-ion) batteries in electrified transportation and portable electronics, and non-lithium battery chemistries emerge as alternatives in special applications from cost and safety views. 6-10 While energy/power

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Section: Flexible Current Collectorsmentioning

confidence: 99%

Advanced energy materials for flexible batteries in energy storage: A review

et al. 2020

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“…According to the current progresses, utilization of Al negative electrodes and graphite positive electrodes has massively decreased the cost of the active materials in the Al batteries. [ 13‐14 ] More importantly, Al electrodes have high gravimetric capacity (2980 mAhg –1 ) and high volumetric capacity (8040 mAhg –1 ), which holds great opportunities for promoting the energy density of the systems.…”

Section: Background and Originality Contentmentioning

confidence: 99%

Initial Electrode Kinetics of Anion Intercalation and De‐intercalation in Nonaqueous Al‐Graphite Batteries^†

Han

Cao

et al. 2020

Chin. J. Chem.

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Graphite electrode | Anion intercalation | Al battery | Electrochemical kinetics | Diffusion Graphitic materials with intercalated sites are considered as the mostly used positive electrode materials in nonaqueous Al batteries. Unlike the small-size cations, the intercalation/de-intercalation of large-size anions into/out of graphite would induce large volume expansion and micro-structure reconfiguration, leading to unexpected coulombic efficiency in the full cells (<95% within initial several cycles). For understanding the irreversible processes induced by anion intercalation/de-intercalation (AlCl 4-), here the kinetics of first two cycles for the Al-graphite batteries have been systematically studied. To study kinetics behaviors at representative states, a combined method upon galvanostatic intermittent titration technique and electrochemical impedance spectroscopy has been carried out. The achieved diffusion coefficients of the positive electrodes assembled with different graphite sizes suggest that size effect also plays a critical role in determining the electrochemical kinetics in the mass transport in both electrolyte and graphitic layers as well as in interface reaction. The morphologies and micro-structures of the post-cycled graphite electrodes have been also experimentally studied, which also well supports the irreversible intercalation/de-intercalation behaviors in graphite electrodes. The results offer a significant platform to well understand the essential factors in tailoring coulombic efficiency from a kinetic view, which would be helpful in promoting the graphite electrodes in Al batteries.

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“…[1][2][3][4] The development of high-energy cathode materials and low-cost and stable electrolytes has been extensively studied for aluminum-ion batteries and aluminum dual-ion batteries (consisting of a carbonaceous cathode). [5][6][7][8][9][10][11][12] However, as a crucial part of aluminum-based batteries, Al anodes have some challenging issues that need to be properly addressed, such as the dendrite growth, insulative oxide film, and corrosion accompanying hydrogen evolution in an ionic liquid (IL) electrolyte. [13][14][15][16] Conventional Al anodes have the limitation of dendrite formation due to unstable reversible deposition, leading to safety concerns when piercing the separator and causing deteriorative capacity and cycling life.…”

Section: Introductionmentioning

confidence: 99%

“…Aluminum–metal secondary batteries show remarkable potential as next‐generation energy storage systems owing to their high theoretical gravimetric capacity (2.98 Ah g −1 ), intrinsic safety, and abundant resource 1–4 . The development of high‐energy cathode materials and low‐cost and stable electrolytes has been extensively studied for aluminum‐ion batteries and aluminum dual‐ion batteries (consisting of a carbonaceous cathode) 5–12 . However, as a crucial part of aluminum‐based batteries, Al anodes have some challenging issues that need to be properly addressed, such as the dendrite growth, insulative oxide film, and corrosion accompanying hydrogen evolution in an ionic liquid (IL) electrolyte 13–16 …”

Section: Introductionmentioning

confidence: 99%

Electrodeposition of a dendrite‐free 3D Al anode for improving cycling of an aluminum–graphite battery

Li¹,

Hui

Ji³

et al. 2021

Carbon Energy

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Aluminum-metal batteries show great potential as next-generation energy storage due to their abundant resources and intrinsic safety. However, the crucial limitations of metallic Al anodes, such as dendrite and corrosion problems in conventional aluminum-metal batteries, remain challenging and elusive. Here, we report a novel electrodeposition strategy to prepare an optimized 3D Al anode on carbon cloth with an uniform deposition morphology, low local current density, and mitigatory volume change. The symmetrical cells with the 3D Al anode show superior stable cycling (>450 h) and low-voltage hysteresis (~170 mV) at 0.5 mA cm −2 . High reversibility (~99.7%) is achieved for the Al plating/stripping. The graphite | | Al-4/CC full batteries show a long lifespan of 800 cycles with 54 mAh g −1 capacity at a high current density of 1000 mA g −1 , benefiting from the high capacitive-controlled distribution. This study proposes a novel strategy to design 3D Al anodes for metallic-Al-based batteries by eliminating the problems of planar Al anodes and realizing the potential applications of aluminum-graphite batteries.

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All-carbon positive electrodes for stable aluminium batteries

Cited by 31 publications

References 43 publications

Advanced energy materials for flexible batteries in energy storage: A review

Advanced energy materials for flexible batteries in energy storage: A review

Initial Electrode Kinetics of Anion Intercalation and De‐intercalation in Nonaqueous Al‐Graphite Batteries^†

Electrodeposition of a dendrite‐free 3D Al anode for improving cycling of an aluminum–graphite battery

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All-carbon positive electrodes for stable aluminium batteries

Cited by 31 publications

References 43 publications

Advanced energy materials for flexible batteries in energy storage: A review

Advanced energy materials for flexible batteries in energy storage: A review

Initial Electrode Kinetics of Anion Intercalation and De‐intercalation in Nonaqueous Al‐Graphite Batteries†

Electrodeposition of a dendrite‐free 3D Al anode for improving cycling of an aluminum–graphite battery

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Initial Electrode Kinetics of Anion Intercalation and De‐intercalation in Nonaqueous Al‐Graphite Batteries^†