Alkynyl derivatives of gold complexes containing C6H3-5-Me-2-EPh2 (E = P, As) ligands

Bhargava, Suresh K.; Kitadai, Kunihiko; Privér, Steven H.; Takahashi, Miwa; Wagler, Jörg

doi:10.1016/j.jorganchem.2010.03.027

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Phosphine Chalcogen and Related Ligands1

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Cited by 9 publications

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“…177 Cyclometallated phosphine and arsine gold(II) dimers were reacted with several bis(alkynes) to give binuclear alkynyl gold(I) complexes. 178 Syntheses and structures of dinuclear silver(I) complexes with arsine and pyridyl ligands 179 as well as bridging bipyrazol ligands 180 were reported. Cyclic phosphinimines can coordinate silver(I) and gold(I) quite similar to carbene ligands.…”

Section: Phosphine Chalcogen and Related Ligandsmentioning

confidence: 99%

Silver and gold

Meyer

Schuh

Mohr

2011

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

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Section: Phosphine Chalcogen and Related Ligandsmentioning

confidence: 99%

Silver and gold

Meyer

Schuh

Mohr

2011

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

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arsination

Crosby¹

2020

Catalysis From a to Z

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(Benzimidazolin‐2‐ylidene)–Au^I–Alkynyl Complexes: Syntheses, Structure, and Photophysical Properties

et al. 2012

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A series of N-heterocyclic carbene-based Au I -σ-acetylide complexes of the type [(Bimz)Au-CϵCR] (Bimz = benzimidazolin-2-ylidene; R = aryl, silyl groups) (1a-1l, 2, 3) were prepared from the precursor [(Bimz)Au I Cl] by an in situ deprotonation of the terminal alkynes. Steady-state photoluminescence studies revealed that most of these complexes exhibit phosphorescence at room temperature and in 77 K rigidified matrices. Molecular structures were determined by single-

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Alkynyl derivatives of gold complexes containing C6H3-5-Me-2-EPh2 (E = P, As) ligands

Cited by 9 publications

References 50 publications

Silver and gold

Silver and gold

arsination

(Benzimidazolin‐2‐ylidene)–Au^I–Alkynyl Complexes: Syntheses, Structure, and Photophysical Properties

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Alkynyl derivatives of gold complexes containing C6H3-5-Me-2-EPh2 (E = P, As) ligands

Cited by 9 publications

References 50 publications

Silver and gold

Silver and gold

arsination

(Benzimidazolin‐2‐ylidene)–AuI–Alkynyl Complexes: Syntheses, Structure, and Photophysical Properties

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Product

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About

(Benzimidazolin‐2‐ylidene)–Au^I–Alkynyl Complexes: Syntheses, Structure, and Photophysical Properties