Alkyloxycarbonyl thiosulfates, a new family of water-soluble acylating agents: amidation and hydrolysis reactions

(15-Crown-5-κ5O)[S-(E)-1,2-dichlorovinyl thiosulfato-κO]sodium

“…For the usage of sodium alkyl thiosulfate in synthesis, see: Crich et al (2007); Cruz et al (2001); Guth et al (1979); Huang et al (1997); Wille et al (1977). For the crystal structure of similiar 15-crown-5 complexes, see: Blais et al (2001); McIntosh et al (2001).…”

“…Data collection: XSCANS (Bruker, 1997); cell refinement: XSCANS; data reduction: XSCANS; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL. -S, C-N, C-O and S-N bonds (Crich et al, 2007;Cruz et al, 2001;Guth et al, 1979;Huang et al, 1997;Wille et al, 1977). However, most of these reactions are carried out under vigorous chemical conditions.…”