Alkoxylation of α, β-unsaturated aldehydes on gold supported on mesoporous anatase

Kenjo, Shota; Yoshitake, Hideaki

doi:10.1016/j.micromeso.2016.09.010

Cited by 3 publications

(2 citation statements)

References 48 publications

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“…For instance, gold nanoparticles have been investigated as catalysts for the production of methyl acrylate from acrolein. Kenjo and co-workers found that when an Au(2h)/MA450 catalyst was used, the optimum selectivity of MA was 78% . Tsutsumi investigated the use of gold nanoparticles supported on CeO 2 for both the production of methyl acrylate and methyl methacrylate .…”

Section: Acrylicsmentioning

confidence: 99%

Polymers without Petrochemicals: Sustainable Routes to Conventional Monomers

et al. 2022

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Access to a wide range of plastic materials has been rationalized by the increased demand from growing populations and the development of high-throughput production systems. Plastic materials at low costs with reliable properties have been utilized in many everyday products. Multibillion-dollar companies are established around these plastic materials, and each polymer takes years to optimize, secure intellectual property, comply with the regulatory bodies such as the Registration, Evaluation, Authorisation and Restriction of Chemicals and the Environmental Protection Agency and develop consumer confidence. Therefore, developing a fully sustainable new plastic material with even a slightly different chemical structure is a costly and long process. Hence, the production of the common plastic materials with exactly the same chemical structures that does not require any new registration processes better reflects the reality of how to address the critical future of sustainable plastics. In this review, we have highlighted the very recent examples on the synthesis of common monomers using chemicals from sustainable feedstocks that can be used as a like-for-like substitute to prepare conventional petrochemical-free thermoplastics.

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Section: Acrylicsmentioning

confidence: 99%

Polymers without Petrochemicals: Sustainable Routes to Conventional Monomers

et al. 2022

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“…Methyl acrylate formation from glycerol can be performed via a two‐step process using separate reactors. The successful synthesis of methyl acrylate from acrolein and methanol has been reported over supported gold nanoparticles, e. g . Au/ZnO, showing 87 % selectivity at 97 % acrolein conversion at ambient conditions .…”

Section: Conversion Of Alkyl Lactates and Derivatives To Alkyl Acrylatesmentioning

confidence: 99%

Bio‐Acrylates Production: Recent Catalytic Advances and Perspectives of the Use of Lactic Acid and Their Derivates

et al. 2018

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The production of drop‐in chemicals from bio‐based renewable sources is gaining a lot of momentum due to proven negative impact of fossil‐based economy on environment and society. In this Review, various bio‐derived platform molecules are assessed as renewable alternatives to fossil resources for the catalytic production of acrylates. Acrylic acid and its esters are key building blocks of a large number of high‐value oligomers and polymers in the current industry. In spite of the encouraging successes reported on gram or lab‐scale, real implementation of bio‐based examples remain scarce mainly due to the current high cost and limited availability of the bio‐based substrates. As lactic acid and their derivatives are one of the most promising feedstocks for bio‐acrylate production, they are the main focus of this Review.

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NH₂-MIL-125(Ti)-derived porous cages of titanium oxides to support Pt–Co alloys for chemoselective hydrogenation reactions

Chen

et al. 2019

Chem. Sci.

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Alkoxylation of α, β-unsaturated aldehydes on gold supported on mesoporous anatase

Cited by 3 publications

References 48 publications

Polymers without Petrochemicals: Sustainable Routes to Conventional Monomers

Polymers without Petrochemicals: Sustainable Routes to Conventional Monomers

Bio‐Acrylates Production: Recent Catalytic Advances and Perspectives of the Use of Lactic Acid and Their Derivates

NH₂-MIL-125(Ti)-derived porous cages of titanium oxides to support Pt–Co alloys for chemoselective hydrogenation reactions

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Alkoxylation of α, β-unsaturated aldehydes on gold supported on mesoporous anatase

Cited by 3 publications

References 48 publications

Polymers without Petrochemicals: Sustainable Routes to Conventional Monomers

Polymers without Petrochemicals: Sustainable Routes to Conventional Monomers

Bio‐Acrylates Production: Recent Catalytic Advances and Perspectives of the Use of Lactic Acid and Their Derivates

NH2-MIL-125(Ti)-derived porous cages of titanium oxides to support Pt–Co alloys for chemoselective hydrogenation reactions

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NH₂-MIL-125(Ti)-derived porous cages of titanium oxides to support Pt–Co alloys for chemoselective hydrogenation reactions